Synthesis and characterization of platinacyclosulfides derived from platinum based heterobimetallic carbonyl clusters

被引：0

作者：

Sravani, Chinduluri ^{[1
]}

Venkatesh, Sadhana ^{[1
]}

Madhesan, H. ^{[1
]}

Vijayakrishna, Kari ^{[1
]}

Aswanikumar, Cherukuri ^{[2
]}

Sivaramakrishna, AkeIla ^{[1
]}

机构：

[1] VIT Univ, Sch Adv Sci, Div Chem, Vellore 632014, Tamil Nadu, India

[2] VIT Univ, Sch Informat Technol, Vellore 632014, Tamil Nadu, India

来源：

JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2015年 / 92卷 / 05期

关键词：

Heterobimetallic carbonyl clusters; reactivity; elemental sulfur; HIGH-YIELD SYNTHESIS; CRYSTAL-STRUCTURE; REACTIVITY; COMPLEXES; LIGAND; CHEMISTRY; DPPE; RU;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The present paper describes the synthesis and reactivity of platinum based trinuclear carbonyl clusters of the type L2PtRu2(CO)(8) where L-2 = 1,3-bis(diphenylphosphino)propane (dppp) and 1,2-bis(diphenylphosphino)butane (dppe). Reaction of these trinuclear clusters with elemental sulfur yielded the unexpected formation of platinacyclosulfides. The products were isolated and identified as platinacyclodisulfide and platinacyclotetrasulfide by analytical and spectroscopic techniques.

引用

页码：787 / 791

页数：5

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