Synthesis and characterization of platinacyclosulfides derived from platinum based heterobimetallic carbonyl clusters

被引：0
|
作者：
Sravani, Chinduluri [1 ]
Venkatesh, Sadhana [1 ]
Madhesan, H. [1 ]
Vijayakrishna, Kari [1 ]
Aswanikumar, Cherukuri [2 ]
Sivaramakrishna, AkeIla [1 ]
机构：
[1] VIT Univ, Sch Adv Sci, Div Chem, Vellore 632014, Tamil Nadu, India
[2] VIT Univ, Sch Informat Technol, Vellore 632014, Tamil Nadu, India
来源：
JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2015年 / 92卷 / 05期
关键词：
Heterobimetallic carbonyl clusters; reactivity; elemental sulfur; HIGH-YIELD SYNTHESIS; CRYSTAL-STRUCTURE; REACTIVITY; COMPLEXES; LIGAND; CHEMISTRY; DPPE; RU;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The present paper describes the synthesis and reactivity of platinum based trinuclear carbonyl clusters of the type L2PtRu2(CO)(8) where L-2 = 1,3-bis(diphenylphosphino)propane (dppp) and 1,2-bis(diphenylphosphino)butane (dppe). Reaction of these trinuclear clusters with elemental sulfur yielded the unexpected formation of platinacyclosulfides. The products were isolated and identified as platinacyclodisulfide and platinacyclotetrasulfide by analytical and spectroscopic techniques.
引用
收藏
页码：787 / 791
页数：5
相关论文
共 50 条
  • [21] Synthesis and characterization of some heterobimetallic complexes of Cu, Zn and Mn derived from succinoyldihydrazones
    Borthakur, K.
    Kumar, A.
    Lal, R. A.
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2015, 92 (07) : 1071 - 1081
  • [22] Ruthenium carbonyl clusters in faujasite cages: Synthesis and characterization
    Shen, GC
    Liu, AM
    Ichikawa, M
    INORGANIC CHEMISTRY, 1998, 37 (21) : 5497 - 5506
  • [23] Synthesis and characterisation of hexaruthenium carbido carbonyl clusters containing arenes derived from biphenyl
    Johnson, BFG
    Shephard, DS
    Braga, D
    Grepioni, F
    Parsons, S
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (19): : 3563 - 3569
  • [24] Synthesis, characterization and toxicity of new heterobimetallic complexes of platinum(II) and palladium(II)
    Sharma, K
    Fahmi, N
    Singh, RV
    APPLIED ORGANOMETALLIC CHEMISTRY, 2001, 15 (03) : 221 - 226
  • [25] Synthesis and structural characterization of an authentic platinum(IV) carbonyl compound
    Fornies, J
    Gomez-Saso, MA
    Martin, A
    Martinez, F
    Menjon, B
    Navarrete, J
    ORGANOMETALLICS, 1997, 16 (26) : 6024 - 6027
  • [26] SYNTHESIS AND STEREOCHEMICAL CHARACTERIZATION OF PLATINUM AND NICKEL CARBONYL CLUSTER ANIONS
    LONGONI, G
    CALABRES.JC
    CHINI, P
    MARTINEN.S
    CAVALIER.A
    DAHL, LF
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1973, : 36 - &
  • [27] THE SYNTHESIS AND CHARACTERIZATION OF A GROUP OF CYCLIC TETRAMERIC PLATINUM CLUSTERS
    PETERSON, ES
    ABBOTT, EH
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 193 : 177 - INOR
  • [28] SYNTHESIS AND CHARACTERIZATION OF PLATINUM AND PALLADIUM CLUSTERS WITH PHOSPHIDE LIGANDS
    MOISEEV, II
    KOZITSYNA, NY
    KOCHUBEY, DI
    KOLOMIJCHUK, VN
    ZAMARAEV, KI
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 451 (1-2) : 231 - 241
  • [29] Distinctive features of supported catalysts prepared from platinum carbonyl clusters
    N. B. Shitova
    V. A. Drozdov
    P. E. Kolosov
    M. D. Smolikov
    Kinetics and Catalysis, 2000, 41 (5) : 720 - 728
  • [30] Distinctive features of supported catalysts prepared from platinum carbonyl clusters
    Shitova, NB
    Drozdov, VA
    Kolosov, PE
    Smolikov, MD
    KINETICS AND CATALYSIS, 2000, 41 (05) : 720 - 728
12345