Simulation of lithium iron phosphate lithiation/delithiation: Limitations of the core-shell model

被引：14
|
作者：
Safari, M. [1 ]
Farkhondeh, M. [1 ]
Pritzker, M. [1 ]
Fowler, M. [1 ]
Han, Taeyoung [2 ]
Chen, Shih-ken [3 ]
机构：
[1] Univ Waterloo, Dept Chem Engn, Waterloo, ON N2L 3G1, Canada
[2] GM R&D Ctr, Vehicle Dev Res Lab, Warren, MI 48090 USA
[3] GM R&D, Elect & Controls Intergrat Lab, Warren, MI 48090 USA
来源：
ELECTROCHIMICA ACTA | 2014年 / 115卷
关键词：
Core-shell; Modeling; LFP; DISCHARGE MODEL; ELECTRODES; TRANSPORT; DYNAMICS; ENERGY;
D O I：
10.1016/j.electacta.2013.10.159
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
In this work the limitations in using the core shell models to simulate the operation of lithium iron phosphate electrodes are discussed and analyzed. The complications arising from the stepwise nature of the core shell model and erroneous predictions of this model for special conditions are detailed. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码：352 / 357
页数：6
相关论文
共 50 条
  • [1] Addressing the Surface Concentration Discontinuity of the Core-Shell Model for Lithium Iron Phosphate Batteries
    Pozzato, Gabriele
    Takahashi, Aki
    Li, Xueyan
    Lee, Donghoon
    Ko, Johan
    Onori, Simona
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2022, 169 (10)
  • [2] Failure modes of hollow core-shell structural active materials during the lithiation-delithiation process
    Ma, Z. S.
    Xie, Z. C.
    Wang, Y.
    Zhang, P. P.
    Pan, Y.
    Zhou, Y. C.
    Lu, C.
    JOURNAL OF POWER SOURCES, 2015, 290 : 114 - 122
  • [3] Dynamic behaviour of core-shell structured Si nanoparticles during lithiation/delithiation cycling at dynamic loadings
    Gao, Xiang
    Yuan, Chunhao
    Xu, Jun
    12TH INTERNATIONAL CONFERENCE ON THE MECHANICAL AND PHYSICAL BEHAVIOUR OF MATERIALS UNDER DYNAMIC LOADING (DYMAT 2018), 2018, 183
  • [4] Core-Shell Enhanced Single Particle Model for Lithium Iron Phosphate Batteries: Model Formulation and Analysis of Numerical Solutions
    Pozzato, Gabriele
    Takahashi, Aki
    Li, Xueyan
    Lee, Donghoon
    Ko, Johan
    Onori, Simona
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2022, 169 (11)
  • [5] Core-Shell Enhanced Single Particle Model for lithium iron phosphate Batteries: Model Formulation and Analysis of Numerical Solutions
    Pozzato, Gabriele
    Takahashi, Aki
    Li, Xueyan
    Lee, Donghoon
    Ko, Johan
    Onori, Simona
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2022, 169 (06)
  • [6] In Situ Lithiation-Delithiation of Mechanically Robust Cu-Si Core-Shell Nanolattices in a Scanning Electron Microscope
    Xia, Xiaoxing
    Di Leo, Claudio V.
    Gu, X. Wendy
    Greer, Julia R.
    ACS ENERGY LETTERS, 2016, 1 (03): : 492 - 499
  • [7] Preparation and electrochemical properties of Co doped core-shell cathode material on a lithium iron phosphate surface
    Liu, Xingzhong
    Zhang, Yue
    Meng, Yanshuang
    Xiao, Mingjun
    Kang, Tai
    Gao, Hongfu
    Huang, Liangbiao
    Zhu, Fuliang
    JOURNAL OF ALLOYS AND COMPOUNDS, 2022, 923
  • [8] Preparation and electrochemical properties of Co doped core-shell cathode material on a lithium iron phosphate surface
    Liu, Xingzhong
    Zhang, Yue
    Meng, Yanshuang
    Xiao, Mingjun
    Kang, Tai
    Gao, Hongfu
    Huang, Liangbiao
    Zhu, Fuliang
    JOURNAL OF ALLOYS AND COMPOUNDS, 2022, 923
  • [9] Insight into the synthesis and tuning of uncoated, core-shell structured lithium nickel phosphate
    Raafat, Leila
    Thorimbert, Fanny
    Diem, Achim M.
    Fenk, Bernhard
    Bill, Joachim
    Burghard, Zaklina
    JOURNAL OF MATERIALS CHEMISTRY A, 2021, 9 (33) : 17923 - 17935
  • [10] Core-shell TFET Developments and TFET Limitations
    Passlack, M.
    Ramvall, P.
    Vasen, T.
    Afzalian, A.
    Thelander, C.
    Dick, K. A.
    Wernersson, L-E
    Doornbos, G.
    Holland, M.
    2019 INTERNATIONAL SYMPOSIUM ON VLSI TECHNOLOGY, SYSTEMS AND APPLICATION (VLSI-TSA), 2019,
12345