Graphene anchored with ZnFe2O4 nanoparticles as a high-capacity anode material for lithium-ion batteries

被引:109
作者
Xia, Hui [1 ,2 ]
Qian, Yanyan [1 ]
Fu, Yongsheng [2 ]
Wang, Xin [2 ]
机构
[1] Nanjing Univ Sci & Technol, Sch Mat Sci & Engn, Nanjing 210094, Jiangsu, Peoples R China
[2] Nanjing Univ Sci & Technol, Key Lab Soft Chem & Funct Mat, Minist Educ, Nanjing 210094, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
Zinc ferrite; Graphene; Anode material; Lithium-ion batteries; Nanocomposite; HIGH-PERFORMANCE; REVERSIBLE CAPACITY; STORAGE; COMPOSITE; FERRITE; HYBRID;
D O I
10.1016/j.solidstatesciences.2012.12.001
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Heterostructured ZnFe2O4-graphene nanocomposites are synthesized by a facile hydrothermal method. The as-prepared ZnFe2O4-graphene nanocomposites are characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET) analysis and galvanostatic charge and discharge measurements. Compared with the pure ZnFe2O4 nanoparticles, the ZnFe2O4-graphene nanocomposites exhibit much larger reversible capacity up to 980 mAh g(-1), greatly improved cycling stability, and excellent rate capability. The superior electrochemical performance of the ZnFe2O4-graphene nanocomposites could be attributed to the synergetic effect between the conducting graphene nanosheets and the ZnFe2O4 nanoparticles. (C) 2012 Elsevier Masson SAS. All rights reserved.
引用
收藏
页码:67 / 71
页数:5
相关论文
共 33 条
[1]   Functional Materials for Rechargeable Batteries [J].
Cheng, Fangyi ;
Liang, Jing ;
Tao, Zhanliang ;
Chen, Jun .
ADVANCED MATERIALS, 2011, 23 (15) :1695-1715
[2]   One-pot synthesis of ZnFe2O4/C hollow spheres as superior anode materials for lithium ion batteries [J].
Deng, Yuanfu ;
Zhang, Qiumei ;
Tang, Shidi ;
Zhang, Leiting ;
Deng, Shengnan ;
Shi, Zhicong ;
Chen, Guohua .
CHEMICAL COMMUNICATIONS, 2011, 47 (24) :6828-6830
[3]   High capacity ZnFe2O4 anode material for lithium ion batteries [J].
Ding, Yu ;
Yang, Yifu ;
Shao, Huixia .
ELECTROCHIMICA ACTA, 2011, 56 (25) :9433-9438
[4]   Preparation and characterization of CoO used as anodic material of lithium battery [J].
Do, JS ;
Weng, CH .
JOURNAL OF POWER SOURCES, 2005, 146 (1-2) :482-486
[5]   Influence of grain size on lithium storage performance of germanium oxide films [J].
Feng, J. K. ;
Lai, M. O. ;
Lu, L. .
ELECTROCHIMICA ACTA, 2012, 62 :103-108
[6]   Raman spectrum of graphene and graphene layers [J].
Ferrari, A. C. ;
Meyer, J. C. ;
Scardaci, V. ;
Casiraghi, C. ;
Lazzeri, M. ;
Mauri, F. ;
Piscanec, S. ;
Jiang, D. ;
Novoselov, K. S. ;
Roth, S. ;
Geim, A. K. .
PHYSICAL REVIEW LETTERS, 2006, 97 (18)
[7]   Combination of cobalt ferrite and graphene: High-performance and recyclable visible-light photocatalysis [J].
Fu, Yongsheng ;
Chen, Haiqun ;
Sun, Xiaoqiang ;
Wang, Xin .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2012, 111 :280-287
[8]   Magnetically Separable ZnFe2O4-Graphene Catalyst and its High Photocatalytic Performance under Visible Light Irradiation [J].
Fu, Yongsheng ;
Wang, Xin .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2011, 50 (12) :7210-7218
[9]   Synthesis and Lithium Storage Mechanism of Ultrafine MoO2 Nanorods [J].
Guo, Bingkun ;
Fang, Xiangpeng ;
Li, Bin ;
Shi, Yifeng ;
Ouyang, Chuying ;
Hu, Yong-Sheng ;
Wang, Zhaoxiang ;
Stucky, Galen D. ;
Chen, Liquan .
CHEMISTRY OF MATERIALS, 2012, 24 (03) :457-463
[10]   Lithium storage in hollow spherical ZnFe2O4 as anode materials for lithium ion batteries [J].
Guo, Xianwei ;
Lu, Xia ;
Fang, Xiangpeng ;
Mao, Ya ;
Wang, Zhaoxiang ;
Chen, Liquan ;
Xu, Xiaoxue ;
Yang, Hong ;
Liu, Yinong .
ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (06) :847-850