MAIN GROUP CHEMISTRY Breaking the limits with silylenes

被引：47
作者：
Driess, Matthias [1 ]
机构：
[1] Tech Univ Berlin, Dept Chem, D-10623 Berlin, Germany
来源：
NATURE CHEMISTRY | 2012年 / 4卷 / 07期
关键词：
D O I：
10.1038/nchem.1387
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The successful synthesis of acyclic silylenes that are isolable at ambient temperature offers striking new opportunities to use stable silylenes for the activation of important small molecules such as dihydrogen and alkanes — hitherto almost completely the domain of transition metals.
引用
收藏
页码：525 / 526
页数：3
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