Carbon capture and high-capacity supercritical fluid processing with supersonic separator: Natural gas with ultra-high CO2 content

被引:14
作者
Arinelli, Lara de Oliveira [1 ]
de Medeiros, Jose Luiz [1 ]
de Melo, Darley Carrijo [2 ]
Teixeira, Alexandre Mendonca [1 ]
Brigagao, George Victor [1 ]
Passarelli, Fabio Menezes [2 ]
Grava, Wilson Mantovani [2 ]
Araujo, Fella de Queiroz F. [1 ]
机构
[1] Univ Fed Rio de Janeiro, Escola Quim, BR-21941909 Rio De Janeiro, RJ, Brazil
[2] PETROBRAS SA, CENPES, BR-21941970 Rio De Janeiro, RJ, Brazil
关键词
Supersonic separator; Supercritical fluid processing; Ultra-high CO2 content; Natural gas conditioning; CO2; removal; freeze-out; AQUEOUS-SOLUTIONS; RECOVERY; OIL; PURIFICATION; SIMULATION; STREAMS; ENERGY;
D O I
10.1016/j.jngse.2019.04.004
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Some deep-water offshore fields produce oil with high gas/oil ratios and ultra-high %CO2 (> 60% mol) with the onus of processing low-grade gas simultaneously handling huge CO2 dispatch goals. Thus, processing solutions are needed to make feasible such high-capacity gas rigs hundreds of kilometers offshore. Feasibility relies on the choices for CO2 capture and adjustment of water and hydrocarbon dew-points of such high flow rate gas. This problem was approached adopting supersonic separators for dew-point adjustments and for CO2 capture on a floating-hub processing 50 MMsm(3)/d of CO2 ultra-rich gas, reinjecting 96% of treated CO2-rich gas for enhanced oil recovery, while reserving 4% as fuel-gas after CO2 abatement to 20% mol for power production. Process alternatives were assessed in terms of power demand and profitability comparing supersonic separator with membrane-permeation for CO2 removal. Results show that 1st supersonic separator for dew-point adjustments of raw gas recycling condensate to the oil-gas-water separator and 2nd supersonic separator for CO2 removal avoiding CO2 freeze-out, give optimum net present value and minimum CO2 emissions. On one hand, these facts are consequences of less compressor investment as 2nd supersonic separator ejects pressurized CO2 condensate requiring 5% less compression power for enhanced oil recovery relatively to the power required by the lowpressure CO2-rich permeate from the membrane-permeation alternative. On the other hand, the best net value of supersonic separator alternative also reflects its highest revenues derived from recycling condensate from 1st supersonic separator entailing 18% higher oil production.
引用
收藏
页码:265 / 283
页数:19
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