Amine-Functionalized MIL-125 with Imbedded Palladium Nanoparticles as an Efficient Catalyst for Dehydrogenation of Formic Acid at Ambient Temperature

被引：179

作者：

Martis, Martin ^{[1
]}

Mori, Kohsuke ^{[1
,2
]}

Fujiwara, Kensei ^{[1
]}

Ahn, Wha-Seung ^{[3
]}

Yamashita, Hiromi ^{[1
,2
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Div Mat & Mfg Sci, 2-1 Yamadaoka, Suita, Osaka 5650871, Japan

[2] Kyoto Univ, ESICB, Unit Elements Strategy Initiat Catalysts & Batter, Kyoto, Japan

[3] Inha Univ, Dept Chem Engn, Inchon 402751, South Korea

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2013年 / 117卷 / 44期

基金：

日本学术振兴会;

关键词：

METAL-ORGANIC FRAMEWORKS; HYDROGEN GENERATION; DECOMPOSITION; PD; MONTMORILLONITE; STORAGE; ARTEMIS; ATHENA;

D O I：

10.1021/jp4069027

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Palladium nanoparticles were immobilized within the pores of metal organic frameworks MIL-125 and amine-functionalized NH2-MIL-125 using photoassisted and ion exchange deposition methods. The resulting materials showed a very high activity for hydrogen production at ambient temperature in comparison to other titanium-based porous materials. The amine groups in NH2-MIL-125 greatly increased the H-2-generating activity and acted as a stabilizer of Pd NPs. The photoassisted deposition method was a more efficient method for producing highly dispersed small NPs in the MOF materials.

引用

页码：22805 / 22810

页数：6

共 44 条

[1] Luminescent metal-organic frameworks [J].

Allendorf, M. D. ;

Bauer, C. A. ;

Bhakta, R. K. ;

Houk, R. J. T. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1330-1352

[2] Efficient Subnanometric Gold-Catalyzed Hydrogen Generation via Formic Acid Decomposition under Ambient Conditions [J].

Bi, Qng-Yuan ;

Du, Xian-Long ;

Liu, Yong-Mei ;

Cao, Yong ;

He, He-Yong ;

Fan, Kang-Nian .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (21) :8926-8933

[3] Hydrogen from formic acid decomposition over Pd and Au catalysts [J].

Bulushev, Dmitri A. ;

Beloshapkin, Sergey ;

Ross, Julian R. H. .

CATALYSIS TODAY, 2010, 154 (1-2) :7-12

[4] Engineering Metal Organic Frameworks for Heterogeneous Catalysis [J].

Corma, A. ;

Garcia, H. ;

Llabres i Xamena, F. X. L. I. .

CHEMICAL REVIEWS, 2010, 110 (08) :4606-4655

[5] Industrial applications of metal-organic frameworks [J].

Czaja, Alexander U. ;

Trukhan, Natalia ;

Mueller, Ulrich .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1284-1293

[6] A New Photoactive Crystalline Highly Porous Titanium(IV) Dicarboxylate [J].

Dan-Hardi, Meenakshi ;

Serre, Christian ;

Frot, Theo ;

Rozes, Laurence ;

Maurin, Guillaume ;

Sanchez, Clement ;

Ferey, Gerard .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (31) :10857-+

[7] Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks [J].

Deng, Hexiang ;

Doonan, Christian J. ;

Furukawa, Hiroyasu ;

Ferreira, Ricardo B. ;

Towne, John ;

Knobler, Carolyn B. ;

Wang, Bo ;

Yaghi, Omar M. .

SCIENCE, 2010, 327 (5967) :846-850

[8] Hybrid porous solids:: past, present, future [J].

Ferey, Gerard .

CHEMICAL SOCIETY REVIEWS, 2008, 37 (01) :191-214

[9] An Amine-Functionalized Titanium Metal-Organic Framework Photocatalyst with Visible-Light-Induced Activity for CO2 Reduction [J].

Fu, Yanghe ;

Sun, Dengrong ;

Chen, Yongjuan ;

Huang, Renkun ;

Ding, Zhengxin ;

Fu, Xianzhi ;

Li, Zhaohui .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (14) :3364-3367

[10] An efficient binuclear catalyst for decomposition of formic acid [J].

Gao, Y ;

Kuncheria, J ;

Yap, GPA ;

Puddephatt, RJ .

CHEMICAL COMMUNICATIONS, 1998, (21) :2365-2366

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