[μ-1κ2O,O′2(η5)-Cyclopentadienylcarboxylato][2(η5)-diphenylphosphinocyclopentadienyl]bis[1,1(η5)tetramethylcyclopentadienyl]iron(II)- titanium(III)

被引:10
作者
Mach, K
Kubista, J
Císarová, I
Stepnicka, P
机构
[1] Charles Univ Prague, Dept Inorgan Chem, CR-12840 Prague 2, Czech Republic
[2] Acad Sci Czech Republ, J Heyrovsky Inst Phys Chem, CR-18223 Prague 8, Czech Republic
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2002年 / 58卷 / 02期
关键词
D O I
10.1107/S0108270101019370
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reacting stoichiometric amounts of 1-(diphenylphosphino)ferrocenecarboxylic acid and [Ti(eta(5)-C5HMe4)(2)(eta(2)-Me3SiC=CSiMe3)] produced the title carboxylatotitanocene complex, [{mu-1kappa(2)O,O':2(eta(5))-C5H4CO2}{2(eta(5))-C5H4P(C6H5)(2)}{1(eta(5))-C5H(CH3)(4)}(2)(FeTiIII)-Ti-II] or [FeTi(C9H13)(2)(C6H4O2)(C17H14P)]. The angle subtended by the Ti/O/O' plane, where O and O' are the donor atoms of the kappa(2)-carboxylate group, and the plane of the carboxyl-substituted ferrocene cyclopentadienyl is 24.93 (6)degrees.
引用
收藏
页码:m116 / m118
页数:3
相关论文
共 14 条
[1]   SIR92 - a program for automatic solution of crystal structures by direct methods [J].
ALTOMARE, A ;
CASCARANO, G ;
GIACOVAZZO, G ;
GUAGLIARDI, A ;
BURLA, MC ;
POLIDORI, G ;
CAMALLI, M .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :435-435
[2]   Outlier treatment in data merging [J].
Blessing, RH .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1997, 30 :421-426
[3]   MAGNETIC EXCHANGE INTERACTIONS PROPAGATED BY SATURATED BRIDGES IN BINUCLEAR DICYCLOPENTADIENYLTITANIUM(III) COMPLEXES [J].
CLAUSS, AW ;
WILSON, SR ;
BUCHANAN, RM ;
PIERPONT, CG ;
HENDRICKSON, DN .
INORGANIC CHEMISTRY, 1983, 22 (04) :628-636
[4]   Diphenylphosphinoacetate, nicotinate and thiophenoxyacetate as bridging ligands in heterometallic complexes involving bis(η-cyclopentadienyl) titanium(IV) and group 10 or 11 metal chlorides.: Crystal structures of [(η-C5H5)2Ti{OC(O)CH2PPh2}2] and [(η-C5H5)2Ti{μ-OC(O)CH2PPh2}2PdCl2] [J].
Edwards, DA ;
Mahon, MF ;
Paget, TJ .
POLYHEDRON, 2000, 19 (07) :757-764
[5]   Ferrocenic acid derivatives: towards rationalizing changes in the electronic and geometric structures [J].
Lin, L ;
Berces, A ;
Kraatz, HB .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 556 (1-2) :11-20
[6]  
*NON BV, 1997, COLLECT
[7]   Processing of X-ray diffraction data collected in oscillation mode [J].
Otwinowski, Z ;
Minor, W .
MACROMOLECULAR CRYSTALLOGRAPHY, PT A, 1997, 276 :307-326
[8]   Preparation and solid-state characterization of nickel(II) complexes with 1′-(diphenylphosphino)ferrocenecarboxylic acid [J].
Pinkas, J ;
Bastl, Z ;
Slouf, M ;
Podlaha, J ;
Stepnicka, P .
NEW JOURNAL OF CHEMISTRY, 2001, 25 (09) :1215-1220
[9]  
POLAHA J, 1995, ORGANOMETALLICS, V15, P543
[10]  
Sheldrick GM, 2015, ACTA CRYSTALLOGR C, V71, P3, DOI [10.1107/S2053229614024218, 10.1107/S0108767307043930]