[μ-1κ2O,O′2(η5)-Cyclopentadienylcarboxylato][2(η5)-diphenylphosphinocyclopentadienyl]bis[1,1(η5)tetramethylcyclopentadienyl]iron(II)- titanium(III)

被引：10
|
作者：
Mach, K
Kubista, J
Císarová, I
Stepnicka, P
机构：
[1] Charles Univ Prague, Dept Inorgan Chem, CR-12840 Prague 2, Czech Republic
[2] Acad Sci Czech Republ, J Heyrovsky Inst Phys Chem, CR-18223 Prague 8, Czech Republic
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2002年 / 58卷 / 02期
关键词：
D O I：
10.1107/S0108270101019370
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reacting stoichiometric amounts of 1-(diphenylphosphino)ferrocenecarboxylic acid and [Ti(eta(5)-C5HMe4)(2)(eta(2)-Me3SiC=CSiMe3)] produced the title carboxylatotitanocene complex, [{mu-1kappa(2)O,O':2(eta(5))-C5H4CO2}{2(eta(5))-C5H4P(C6H5)(2)}{1(eta(5))-C5H(CH3)(4)}(2)(FeTiIII)-Ti-II] or [FeTi(C9H13)(2)(C6H4O2)(C17H14P)]. The angle subtended by the Ti/O/O' plane, where O and O' are the donor atoms of the kappa(2)-carboxylate group, and the plane of the carboxyl-substituted ferrocene cyclopentadienyl is 24.93 (6)degrees.
引用
收藏
页码：m116 / m118
页数：3
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