Morphology study of poly(gamma-benzyl L-glutamate) and polyisoprene copolymer by pulsed proton NMR

被引:2
|
作者
Yoda, R
Shimoda, M
Komatsuzaki, S
Hayashi, T
Nishi, T
机构
[1] UNIV OSAKA PREFECTURE,ADV SCI & TECHNOL RES INST,SAKAI,OSAKA 593,JAPAN
[2] UNIV TOKYO,FAC ENGN,DEPT APPL PHYS,BUNKYO KU,TOKYO 113,JAPAN
关键词
D O I
10.1016/S0014-3057(96)00281-9
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Morphology study of poly(gamma-benzyl L-glutamate) (PBLG) and polyisoprene (PI) block copolymer using pulsed NMR and electron microscope revealed that the solid block copolymer is in microphase separated state. NMR measurement detected the interface of the block copolymer. Spin-lattice relaxation time T-1 of the block copolymer gave the domain size which is in good agreement with the result obtained from the electron microscopy. (C) 1997 Elsevier Science Ltd.
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页码:815 / 821
页数:7
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