Determination of low molecular weight aliphatic amines by HPLC in environmental water samples

被引：0
作者：
Djozan, D
FarajZadeh, MA
机构：
来源：
HRC-JOURNAL OF HIGH RESOLUTION CHROMATOGRAPHY | 1996年 / 19卷 / 11期
关键词：
high performance liquid chromatography; solid phase extraction; low molecular weight aliphatic amines; fluorescamine (fluram); environmental waters;
D O I：
暂无
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A high resolution liquid chromatographic method is described for determination of low molecular weight (LMW) aliphatic amines in environmental waters. The analytes after isolation are derivatized by fluram and separated with isocratic elution on octyl (C-8) column, followed by fluorimetric detection in 395/495 nm. Different isolation procedures such as octadecylsilane (ODS) and strong cation exchanger (SCX) solid phase extraction (SPE) cartridges and Amberlite CG-120 resin were evaluated. The quantitative characteristics such as recovery, linear dynamic range, correlation coefficient, limit of detection (LOD), and relative standard deviation (RSD) are presented. Using this method, aliphatic amines were analyzed in rain and tap water as well as in waste water.
引用
收藏
页码：633 / 638
页数：6
相关论文
共 30 条
[1]   FLUORESCENCE REAGENTS FOR HIGH-SENSITIVITY CHROMATOGRAPHIC MEASUREMENTS OF PRIMARY AMINES [J].
BEALE, SC ;
SAVAGE, JC ;
WIESLER, D ;
WIETSTOCK, SM ;
NOVOTNY, M .
ANALYTICAL CHEMISTRY, 1988, 60 (17) :1765-1769
[2]   AMMONIUM DETECTION USING AN ION-SELECTIVE ELECTRODE ARRAY IN FLOW-INJECTION ANALYSIS [J].
DEVITERI, FJS ;
DIAMOND, D .
ELECTROANALYSIS, 1994, 6 (01) :9-16
[3]  
DJOZAN D, 1995, CHROMATOGRAPHIA, V41, P568, DOI 10.1007/BF02269721
[4]   THE USE OF FLUORESCAMINE (FLURAM) IN FLUOROMETRIC TRACE ANALYSIS OF PRIMARY AMINES OF PHARMACEUTICAL AND BIOLOGICAL INTEREST [J].
DJOZAN, D ;
FARAJZADEH, MA .
JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS, 1992, 10 (10-12) :1063-1067
[5]  
EREMINA LD, 1993, ZH ANAL KHIM, V48, P35
[6]  
EVGENEV MI, 1993, ZH ANAL KHIM, V48, P1226
[7]   HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHIC METHOD TO DETERMINE AMMONIUM ION AND PRIMARY AMINES IN SEAWATER [J].
GARDNER, WS ;
STJOHN, PA .
ANALYTICAL CHEMISTRY, 1991, 63 (05) :537-540
[8]   SEPARATION OF N-CONTAINING SPECIES BY MEANS OF A NEW VERSATILE ION INTERACTION RP-HPLC METHODOLOGY [J].
GENNARO, MC ;
BERTOLO, PL .
JOURNAL OF LIQUID CHROMATOGRAPHY, 1990, 13 (10) :2059-2075
[9]   SIMULTANEOUS DETERMINATION OF NITRITES, NITRATES AND AMINES BY ION-INTERACTION REVERSED-PHASE HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY - APPLICATION TO LAGOON WATER [J].
GENNARO, MC ;
BERTOLO, PL .
JOURNAL OF CHROMATOGRAPHY, 1990, 509 (01) :147-156
[10]  
GLADILOVICH DB, 1994, ZH ANAL KHIM, V49, P583
123