Influence of coating MgO with coprecipitation method on sticking during fluidized bed reduction of Fe2O3 particles

被引:19
作者
Guo, Lei [1 ]
Zhong, Yiwei [1 ]
Gao, Jintao [1 ]
Yang, Zerong [1 ]
Guo, Zhancheng [1 ]
机构
[1] Univ Sci & Technol Beijing, State Key Lab Adv Met, Beijing 100083, Peoples R China
基金
中国国家自然科学基金;
关键词
Fluidized-bed reduction; Defluidization; Particle; Coprecipitation; Coating; Magnesium oxide; GASEOUS REDUCTION; MAGNESIUM; CO; CARBONATE; SULFUR;
D O I
10.1016/j.powtec.2015.06.067
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Pure Fe2O3 particles were coated with MgO using coprecipitation method under different conditions. For the aim of improving the coating amount and uniformity, the coprecipitation coating method was firstly studied to avoid sticking during fluidized reduction of iron ore. The actual coating amount on the particle surface was quantitatively determined, the sticking problem during fluidizing reduction can be avoided with a MgO coating amount around 0.411 wt.%. The coating amount of MgO on the particle did not decrease after fluidized reduction. Samples were analyzed using (SEM/EDS) analysis, it was found that the MgO coating was effective and intact and merely no exposed part on the Fe2O3 particle surface. The coating uniformity was improved comparing to other coating methods. Precipitates of different crystal structures and morphology generated with different precipitation conditions tend to nucleated at the bottom part of the Fe2O3 particle as the nucleation energy there is lower. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:210 / 217
页数:8
相关论文
共 25 条
[1]   Preparation of a magnesium hydroxy carbonate from magnesium hydroxide [J].
Botha, A ;
Strydom, CA .
HYDROMETALLURGY, 2001, 62 (03) :175-183
[2]   Effects of Temperature on the Preparation of Magnesium Carbonate Hydrates by Reaction Of MgCl2 with Na2CO3 [J].
Cheng Wenting ;
Li Zhibao ;
Demopoulos, George P. .
CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2009, 17 (04) :661-666
[3]  
CHINJE UF, 1986, IRONMAK STEELMAK, V13, P3
[4]   Gaseous reduction of MgO-doped Fe2O3 compacts with carbon-monoxide at 1173-1473 K [J].
ElGeassy, AA .
ISIJ INTERNATIONAL, 1996, 36 (11) :1328-1337
[5]  
GRANSDEN JF, 1974, CAN METALL QUART, V13, P649
[6]   Influence of gaseous sulfur on CO reduction of wustite added with foreign oxides [J].
Hayashi, S ;
Iguchi, Y .
ISIJ INTERNATIONAL, 1996, 36 (08) :1000-1008
[7]   FACTORS AFFECTING THE STICKING OF FINE IRON-ORES DURING FLUIDIZED-BED REDUCTION [J].
HAYASHI, S ;
IGUCHI, Y .
ISIJ INTERNATIONAL, 1992, 32 (09) :962-971
[8]   INFLUENCE OF COATING OXIDE AND SULFUR PRESSURE ON STICKING DURING FLUIDIZED-BED REDUCTION OF IRON-ORES [J].
HAYASHI, S ;
SAWAI, S ;
IGUCHI, Y .
ISIJ INTERNATIONAL, 1993, 33 (10) :1078-1087
[9]   Isothermal reduction kinetics of Fe2O3 mixed with 1-10% Cr2O3 at 1173-1473 K [J].
Khedr, MH .
ISIJ INTERNATIONAL, 2000, 40 (04) :309-314
[10]  
Komatina M., 2004, Metalurgija, V10, P309, DOI [10.30544/378, DOI 10.30544/378]