Polyacrylonitrile-derived nanostructured carbon materials

被引：107
作者：
Kopec, Maciej [1 ,6 ]
Lamson, Melissa [1 ]
Yuan, Rui [1 ]
Tang, Chuanbing [2 ]
Kruk, Michal [3 ,4 ]
Zhong, Mingjiang [5 ]
Matyjaszewski, Krzysztof [1 ]
Kowalewski, Tomasz [1 ]
机构：
[1] Carnegie Mellon Univ, Dept Chem, Ctr Macromol Engn, 4400 Fifth Ave, Pittsburgh, PA 15213 USA
[2] Univ South Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA
[3] CUNY Coll Staten Isl, Dept Chem, 2800 Victory Blvd, Staten Isl, NY 10314 USA
[4] CUNY, Grad Ctr, PhD Program Chem, 365 5thAve, New York, NY 10016 USA
[5] Yale Univ, Dept Chem & Environm Engn, 17 Hillhouse Ave, New Haven, CT 06511 USA
[6] Univ Twente, MESA Inst Nanotechnol, Mat Sci & Technol Polymers, POB 217, NL-7500 Enschede, Netherlands
来源：
PROGRESS IN POLYMER SCIENCE | 2019年 / 92卷
关键词：
Polyacrylonitrile; Controlled radical polymerization; Block copolymers; Templated synthesis; Nitrogen-doped nanocarbons; TRANSFER RADICAL POLYMERIZATION; FRAGMENTATION CHAIN-TRANSFER; NITROGEN-ENRICHED NANOCARBONS; OXYGEN REDUCTION REACTION; HIGH-MOLECULAR-WEIGHT; WELL-DEFINED POLYACRYLONITRILE; TRANSFER RAFT POLYMERIZATION; COMPOSITE CATHODE MATERIALS; ORDERED MESOPOROUS CARBONS; GAMMA-RAY IRRADIATION;
D O I：
10.1016/j.progpolymsci.2019.02.003
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
An overview on polyacrylonitrile (PAN)-derived carbon nanomaterials is presented. Controlled synthesis of well-defined PAN by reversible deactivation radical polymerization (RDRP) techniques is discussed as a route to tailored carbon precursors of various architectures, such as block copolymers (BCPs) and organic-inorganic hybrids. Primary examples of different approaches to templating include the use of PAN-containing BCPs self-assembled on planar surfaces or in solution to yield: (i) bulk carbon films, (ii) discrete nano-objects and (iii) mesoporous copolymer-templated nanocarbons (CTNC5). Inorganic templates or electrospinning as a viable approach to ordered mesoporous carbons or carbon nanofibers are also discussed. Special attention is devoted to nitrogen doping in PAN-derived partially graphitic carbons and to the evaluation of nitrogen-enriched nanocarbons in energy conversion and storage applications such as supercapacitors, lithium-sulfur batteries, electrocatalysts, solar cells or CO2 sorbents. (C) 2019 Elsevier B.V. All rights reserved.
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页码：89 / 134
页数：46
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