Nanostructure CdS/ZnO heterojunction configuration for photocatalytic degradation of Methylene blue

被引:85
作者
Velanganni, S. [1 ]
Pravinraj, S. [2 ]
Immanuel, P. [2 ]
Thiruneelakandan, R. [1 ]
机构
[1] Anna Univ, Dept Chem, Bharathidasan Inst Technol BIT Campus, Tiruchirappalli 620024, Tamil Nadu, India
[2] Anna Univ, Dept Phys, Bharathidasan Inst Technol BIT Campus, Tiruchirappalli 620024, Tamil Nadu, India
关键词
Wet chemistry; ZnO nanostructures; CdS nanoparticles; Photocatalytic degradation; ZNO NANOROD ARRAY; OPTICAL-PROPERTIES; CDS; NANOPARTICLES; NANOWIRE; HETEROSTRUCTURE; NANOCRYSTALS; TEMPERATURE; PERFORMANCE; EFFICIENCY;
D O I
10.1016/j.physb.2018.01.027
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
In the present manuscript, thin films of Zinc Oxide (ZnO) have been deposited on a FTO substrate using a simple successive ionic layer adsorption and reaction (SILAR) and chemical bath deposition (CBD) method. Cadmium Sulphide (CdS) nanoparticles are sensitized over ZnO thin films using SILAR method. The synthesized nano-structured CdS/ZnO heterojunction thin films was characterized by X-ray diffraction (XRD), Scanning electron microscopy (SEM), High resolution transmission electron microscopy (HR-TEM), X-ray photoelectron spectroscopy (XPS), UV-Vis spectroscopy and Raman spectroscopy techniques. The band gap of CdS nanoparticles over ZnO nanostructure was found to be about 3.20 eV. The photocatalytic activities of the deposited CdS/ZnO thin films were evaluated by the degradation of methylene blue (MB) in an aqueous solution under sun light irradiation.
引用
收藏
页码:56 / 62
页数:7
相关论文
共 52 条
[1]   Influence of pH on structural, morphological and optical properties of chemically deposited nanocrystalline ZnO thin films [J].
Amalraj, A. Sales ;
Dharani, A. P. ;
Inbaraj, P. Fermi Hilbert ;
Sivakumar, V. ;
Senguttuvan, G. .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2015, 26 (11) :8877-8886
[2]   Photocatalytic degradation of methylene blue by C3N4/ZnO: the effect of the melamine/ZnO ratios [J].
Amornpitoksuk, Pongsaton ;
Suwanboon, Sumetha ;
Sirimahachai, Uraiwan ;
Randorn, Chamnan ;
Yaemsunthorn, Kasidid .
BULLETIN OF MATERIALS SCIENCE, 2016, 39 (06) :1507-1513
[3]  
Baeissa E S., 2016, Front. Nanosci. Nanotechnol, DOI [DOI 10.15761/FNN.1000134, 10.15761/fnn.1000134]
[4]   Synthesis of visible-light responsive CdS/ZnO nanocomposite photocatalysts via simple precipitation method [J].
Chaengchawi, Potjanaporn ;
Serivalsatit, Karn ;
Sujaridworakun, Pornapa .
TRADITIONAL AND ADVANCED CERAMICS, 2014, 608 :224-229
[5]   Nanostructure sensitization of transition metal oxides for visible-light photocatalysis [J].
Chen, Hongjun ;
Wang, Lianzhou .
BEILSTEIN JOURNAL OF NANOTECHNOLOGY, 2014, 5 :696-710
[6]   RAMAN EFFECT IN ZINC OXIDE [J].
DAMEN, TC ;
PORTO, SPS ;
TELL, B .
PHYSICAL REVIEW, 1966, 142 (02) :570-&
[7]   Effect of film thickness on the energy band gap of nanocrystalline CdS thin films analyzed by spectroscopic ellipsometry [J].
Das, N. S. ;
Ghosh, P. K. ;
Mitra, M. K. ;
Chattopadhyay, K. K. .
PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES, 2010, 42 (08) :2097-2102
[8]   CONDUCTION IN NON-CRYSTALLINE SYSTEMS .5. CONDUCTIVITY, OPTICAL ABSORPTION AND PHOTOCONDUCTIVITY IN AMORPHOUS SEMICONDUCTORS [J].
DAVIS, EA ;
MOTT, NF .
PHILOSOPHICAL MAGAZINE, 1970, 22 (179) :903-&
[9]  
Dumbrava A, 2016, CHALCOGENIDE LETT, V13, P105
[10]   The enhancement of ZnO nanowalls photoconductivity induced by CdS nanoparticle modification [J].
Fang, F. ;
Zhao, D. X. ;
Li, B. H. ;
Zhang, Z. Z. ;
Zhang, J. Y. ;
Shen, D. Z. .
APPLIED PHYSICS LETTERS, 2008, 93 (23)