Improvement of the catalytic stability of molybdenum carbide via encapsulation within carbon nanotubes in dry methane reforming

被引：35
作者：
Gao, Haifeng [1 ]
Yao, Zhiwei [1 ]
Shi, Yan [1 ]
Wang, Siqi [1 ]
机构：
[1] Liaoning Shihua Univ, Coll Chem Chem Engn & Environm Engn, Fushun 113001, Peoples R China
来源：
CATALYSIS SCIENCE & TECHNOLOGY | 2018年 / 8卷 / 03期
基金：
中国国家自然科学基金;
关键词：
HYDROGEN-PRODUCTION; SYNTHESIS GAS; TUNGSTEN CARBIDES; DIOXIDE; NI; DECOMPOSITION; OXYNITRIDES; TEMPERATURE; PERFORMANCE; CONVERSION;
D O I：
10.1039/c7cy02506h
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We reported for the first time the enhancement of the oxidation resistance of Mo2C nanoparticles by encapsulation within carbon nanotubes (CNTs). The oxidation rate of Mo2C can be reduced significantly by the encapsulated Mo2C in CH4/CO2 reforming, which promoted the catalytic stability of Mo2C. This type of Mo2C/CNTs modified by Ni (Co) showed a high catalytic stability at a high WHSV (18 000 cm(3) g(-1) h(-1)) throughout a 50 h period.
引用
收藏
页码：697 / 701
页数：5
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