New structural units in molybdenum oxyfluoride chemistry

被引：13
作者：
Aldous, David W.
Lightfoot, Philip [1 ]
机构：
[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
来源：
JOURNAL OF FLUORINE CHEMISTRY | 2012年 / 144卷
基金：
英国工程与自然科学研究理事会;
关键词：
Molybdenum oxyfluoride; Solvothermal synthesis; Metal-metal bonding; Crystal structure; CRYSTAL-STRUCTURE; HYDROTHERMAL SYNTHESIS; VANADIUM OXYFLUORIDES; CLUSTER; OXOFLUORO; SPECTRA; SOLIDS; ANIONS; BONDS; OXIDE;
D O I：
10.1016/j.jfluchem.2012.07.018
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The solvothermal syntheses and crystal structures of five new molybdenum oxyfluorides are presented. These exhibit three novel structural units, each containing Mo in a reduced oxidation state: a dimeric [MO2O4F2(C2H8N2)(2)] unit (Mo4+), a tetrameric [Mo4O8F10](6-) unit (Mo5+) and an infinite chain [MoOF3](-) unit (Mo4+). Mo-Mo bonding is observed in each of the new building units. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：108 / 113
页数：6
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