Preparation of Tetraethylenepentamine Modified Magnetic Graphene Oxide for Adsorption of Dyes from Aqueous Solution

被引:9
作者
Tang, Xiaosheng [1 ,2 ,3 ]
Tang, Ping [4 ,5 ]
Liu, Liangliang [4 ]
机构
[1] Hubei Normal Univ, Hubei Key Lab Edible Wild Plants Conservat & Util, Huangshi 435002, Hubei, Peoples R China
[2] Hubei Normal Univ, Natl Demonstrat Ctr Expt Biol Educ, Huangshi 435002, Hubei, Peoples R China
[3] Hubei Normal Univ, Coll Life Sci, Hubei Key Lab Pollutant Anal & Reuse Technol, Huangshi 435002, Hubei, Peoples R China
[4] Chinese Acad Agr Sci, Inst Bast Fiber Crops, Changsha 410205, Hunan, Peoples R China
[5] Hubei Polytech Univ, Sch Environm Sci & Engn, Hubei Key Lab Mine Environm Pollut Control & Reme, Huangshi 435003, Hubei, Peoples R China
关键词
adsorption; dye; graphene oxide; magnetic nanoparticles; tetraethylenepentamine; ACID RED 18; EFFICIENT ADSORPTION; ANIONIC DYES; REMOVAL; NANOCOMPOSITE; COMPOSITE;
D O I
10.21577/0103-5053.20170145
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this study, tetraethylenepentamine modified magnetic graphene oxide nanomaterial (TMGO) was prepared and characterized by transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS) and vibration sample magnetometer (VSM). All the characterizations proved that the modification and preparation of TMGO were successful. The TMGO nanomaterial was used in the adsorption of Acid Red 18 (AR) in aqueous solution. The parameters like pH of solution, adsorption kinetics and isotherms were all investigated. The results indicated that the TMGO nanomaterial had satisfied adsorption ability and the maximum adsorption capacity was 524.2 mg g(-1) at 45 degrees C and pH 6. The adsorption capacity remained at 91.8% of the initial value after five cycles. The adsorption process with AR was found through fitting the pseudo-second-order kinetics equations and the Freundlich adsorption model. The experimental results demonstrated that the TMGO nanomaterial could be rapidly extracted from the medium and had a good adsorption ability to remove dyes in wastewater.
引用
收藏
页码:334 / 342
页数:9
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