Moisture dependence of thermal expansion in cement-based materials at early ages

The coefficient of thermal expansion (CTE) of cement-based materials is strongly dependent upon their moisture content. In particular, with a drop of internal relative humidity (RH), an increase of the CTE is observed. This effect can be attributed to the internal RH change associated with a temperature change (Delta RH/Delta T coefficient). Published data show high scatter and moreover they mostly refer to drying and do not address the effect of self-desiccation in low water-to-cement ratio (w/c) materials. In this paper, the RH dependence upon temperature is quantified using the Delta RH/Delta T coefficient for cement pastes of different w/c. Next, the Delta RH/Delta T coefficient is coupled with the observed evolution of the CTE in cement pastes and mortars. The experimental investigation focuses explicitly on the early-age period up to about 7 days from water addition. (C) 2013 Elsevier Ltd. All rights reserved.