Synthesis and structures of the ligands 1-methylimidazol-2-yl(pyridin-2-yl)methanone {(py)(mim)CO} and 1-benzylimidazol-2-yl(1-phenylaldimine) (PhN=CHbim) as their tetracarbonylmolybdenum(0) complexes [Mo(CO)4(L2-N,N′)]

被引：0

作者：

Batten, MP

Canty, AJ ^{[1
]}

Cavell, KJ

Skelton, BW

White, AH

机构：

[1] Univ Tasmania, Sch Chem, Hobart, Tas 7001, Australia

[2] Univ Western Australia, Sch Biomed & Chem Sci, Perth, WA 6009, Australia

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2006年 / 632卷 / 05期

关键词：

molybdenum; carbonyl; imidazole; crystal structure;

D O I：

10.1002/zaac.200500531

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes [Mo(CO)(4)(L-2-N,N')] [L-2 = 1-methylimidazol -2-yl (pyridin-2-yl) met ban one and 1-benzylimidazol-2-yl(1-phenylaldimine)] have been synthesized from hexacarbonylmolybdenum(0) in order to define the coordination characteristics of the bidentate nitrogen-donor ligands; the complexes exhibit distorted octahedral coordination for molybdenum(0) and cis-bidentate ligand configurations.

引用

页码：876 / 878

页数：3

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