Synthesis and structures of the ligands 1-methylimidazol-2-yl(pyridin-2-yl)methanone {(py)(mim)CO} and 1-benzylimidazol-2-yl(1-phenylaldimine) (PhN=CHbim) as their tetracarbonylmolybdenum(0) complexes [Mo(CO)4(L2-N,N′)]

被引：0
|
作者：
Batten, MP
Canty, AJ [1 ]
Cavell, KJ
Skelton, BW
White, AH
机构：
[1] Univ Tasmania, Sch Chem, Hobart, Tas 7001, Australia
[2] Univ Western Australia, Sch Biomed & Chem Sci, Perth, WA 6009, Australia
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2006年 / 632卷 / 05期
关键词：
molybdenum; carbonyl; imidazole; crystal structure;
D O I：
10.1002/zaac.200500531
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complexes [Mo(CO)(4)(L-2-N,N')] [L-2 = 1-methylimidazol -2-yl (pyridin-2-yl) met ban one and 1-benzylimidazol-2-yl(1-phenylaldimine)] have been synthesized from hexacarbonylmolybdenum(0) in order to define the coordination characteristics of the bidentate nitrogen-donor ligands; the complexes exhibit distorted octahedral coordination for molybdenum(0) and cis-bidentate ligand configurations.
引用
收藏
页码：876 / 878
页数：3
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