Recent Advances in Metal-Catalyzed Asymmetric Mannich Reactions

被引：104
|
作者：
Karimi, Babak [1 ]
Enders, Dieter [2 ]
Jafari, Ehsan [1 ]
机构：
[1] IASBS, Dept Chem, Gava Zang, Zanjan, Iran
[2] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany
来源：
SYNTHESIS-STUTTGART | 2013年 / 45卷 / 20期
关键词：
asymmetric Mannich reaction; aza-Henry reactions; vinylogous Mannich reactions; carbon-carbon bond-forming reactions; metal complexes; AZA-HENRY REACTION; PHOSPHINE-OXAZOLINE LIGANDS; ENANTIOSELECTIVE VINYLOGOUS MANNICH; CHIRAL ZIRCONIUM CATALYSTS; BETA-AMINO; GLYCINE DERIVATIVES; HIGHLY EFFICIENT; DIELS-ALDER; STEREOSELECTIVE-SYNTHESIS; BIS(OXAZOLINE) LIGANDS;
D O I：
10.1055/s-0033-1339479
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In this review, recent works on metal-catalyzed asymmetric Mannich, aza-Henry and vinylogous Mannich reactions are described. The asymmetric Mannich reaction is one of the most powerful methodologies among the carbon-carbon bond-forming reactions, and provides direct access to a wide range of optically active natural products with useful biological properties.
引用
收藏
页码：2769 / 2812
页数：44
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