Alcohol responsive 2D coordination network of 3-(4-pyridyl)benzoate and Zinc(II)

被引：8
|
作者：
Mehlana, Gift [1 ]
Ramon, Gaelle [1 ]
Bourne, Susan A. [1 ]
机构：
[1] Univ Cape Town, Dept Chem, Ctr Supramol Chem Res, ZA-7701 Rondebosch, South Africa
来源：
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS | 2013年 / 228卷 / 07期
基金：
新加坡国家研究基金会;
关键词：
Coordination network; Guest exchange; Thermal analysis; Alcohol sorption; METAL-ORGANIC FRAMEWORK; SORPTION; ARCHITECTURES; SEPARATION; DATABASE;
D O I：
10.1524/zkri.2013.1607
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The solvothermal reaction of 3-(4-pyridyl)benzoic acid and zinc nitrate yielded a 2D network with an sql topology. Both elemental analysis and single crystal X-ray diffraction studies confirmed the formula of the compound as {[Zn(34pba)(2)] center dot (0.5 DMF) center dot (0.5 H2O)}(n) (1). At room temperature, the desolvated phase of 1, 1d, absorbs methanol, ethanol, 1-propanol and 1-butanol but not water vapour.
引用
收藏
页码：318 / 322
页数：5
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