A novel process for simultaneous degumming and deacidification of Soybean, Canola and Sunflower oils by tetrabutylphosphonium phosphate ionic liquid

被引：11

作者：

Adhami, Khavar ^{[1
]}

Asadollahzadeh, Hamideh ^{[1
]}

Ghazizadeh, Mandieh ^{[1
]}

机构：

[1] Islamic Azad Univ, Kerman Branch, Dept Chem, Kerman, Iran

来源：

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | 2019年 / 76卷

关键词：

Deacidification; Degumming; Ionic liquid; Free fatty acid; Tetrabutylphosphonium phosphate; THERMOPHYSICAL PROPERTIES; PHYSICAL-PROPERTIES; VEGETABLE-OILS; TEMPERATURE; ACID; EXTRACTION; SEPARATION; SOLVENT;

D O I：

10.1016/j.jiec.2019.03.048

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this study simultaneous degumming and deacidification of edible oils were done by tetrabutylphosphonium phosphate IL. Under the optimized extraction conditions of soybean oil (3 mass% IL, 60 degrees C and 20 min), canola oil (2 mass% IL, 60 degrees C and 20 min) and sunflower oil (1.5 mass% IL, 50 degrees C, 15 min), the content of free fatty acid (FFA) and phosphorus reached 0.18% and 3.5 mg/kg; 0.12% and 3.8 mg/kg; and 0.17% and 3.5 mg/kg, respectively. In this work, soap stock and water washing stage were eliminated and no waste water, which pollutes the environment, was produced. (C) 2019 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

引用

页码：245 / 250

页数：6

共 40 条

[1] Synthesis and evaluation of bio-compatible cholinium amino acid ionic liquids for lubrication applications [J].

Aathira, M. S. ;

Khatri, Praveen K. ;

Jain, Suman L. .

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2018, 64 :420-429

[2] Density, Refraction Index, and Vapor-Liquid Equilibria of n-Methyl-2-hydroxyethylammonium Hexanoate Plus (Methyl Acetate, Ethyl Acetate, or Propyl Acetate) at Several Temperatures [J].

Alvarez, V. H. ;

Mattedi, S. ;

Aznar, M. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (44) :14543-14554

[3] Removal of naphthenic acids from crude oil using amino acid ionic liquids [J].

Anderson, K. ;

Goodrich, P. ;

Hardacre, C. ;

Hussain, A. ;

Rooney, D. W. ;

Wassell, D. .

FUEL, 2013, 108 :715-722

[4] In situ solvent formation microextraction based on ionic liquids: A novel sample preparation technique for determination of inorganic species in saline solutions [J].

Baghdadi, Majid ;

Shemirani, Farzaneh .

ANALYTICA CHIMICA ACTA, 2009, 634 (02) :186-191

[5] Enhanced CO2 separation selectivity in oligo(ethylene glycol) functionalized room-temperature ionic liquids [J].

Bara, Jason E. ;

Gabriel, Christopher J. ;

Lessmann, Sonja ;

Carlisle, Trevor K. ;

Finotello, Alexia ;

Gin, Douglas L. ;

Noble, Richard D. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2007, 46 (16) :5380-5386

[6] New approaches in deacidification of edible oils - a review [J].

Bhosle, BM ;

Subramanian, R .

JOURNAL OF FOOD ENGINEERING, 2005, 69 (04) :481-494

[7] Separation of ionic liquid dispersions in centrifugal solvent extraction contactors [J].

Birdwell, Joseph F., Jr. ;

McFarlane, Joanna ;

Hunt, Rodney D. ;

Luo, Huimin ;

DePaoli, David W. .

SEPARATION SCIENCE AND TECHNOLOGY, 2006, 41 (10) :2205-2223

[8] Extraction of butyric acid with a solvent containing ammonium ionic liquid [J].

Blahusiak, Marek ;

Schlosser, Stefan ;

Martak, Jan .

SEPARATION AND PURIFICATION TECHNOLOGY, 2013, 119 :102-111

[9] MALDI-TOF mass spectrometry detection of extra-virgin olive oil adulteration with hazelnut oil by analysis of phospholipids using an ionic liquid as matrix and extraction solvent [J].

Calvano, Cosima D. ;

De Ceglie, Cristina ;

D'Accolti, Lucia ;

Zambonin, Carlo G. .

FOOD CHEMISTRY, 2012, 134 (02) :1192-1198

[10] Preparation and characterization of a novel benzimidazolium bronsted acidic ionic liquid and its application in esterifications [J].

Chen, Shuan-Hu ;

Zhao, Qiong ;

Xu, Xue-Wang .

JOURNAL OF CHEMICAL SCIENCES, 2008, 120 (05) :481-483

← 1 2 3 4 →