Production of nanocrystalline cellulose from lignocellulosic biomass: Technology and applications

被引:784
作者
Brinchi, L. [1 ]
Cotana, F. [1 ]
Fortunati, E. [2 ]
Kenny, J. M. [2 ,3 ]
机构
[1] Univ Perugia, CRB, Ctr Ric Biomasse, I-06125 Perugia, Italy
[2] Univ Perugia, UdR INSTM, Mat Engn Ctr, I-05100 Terni, Italy
[3] ICTP CSIC, Inst Polymer Sci & Technol, Madrid 28006, Spain
关键词
Lignocellulosic biomass; Cellulose; Nanocellulose; Nanotechnology; Nanocomposites; NONISOTHERMAL COLD CRYSTALLIZATION; POLYMER NANOCOMPOSITES; MICROCRYSTALLINE CELLULOSE; NANOFIBER COMPOSITES; SILVER NANOPARTICLES; POLY(VINYL ALCOHOL); POLYVINYL-ALCOHOL; LIGHT-SCATTERING; ACID-HYDROLYSIS; ATOMIC-FORCE;
D O I
10.1016/j.carbpol.2013.01.033
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The use of renewables materials for industrial applications is becoming impellent due to the increasing demand of alternatives to scarce and unrenewable petroleum supplies. In this regard, nanocrystalline cellulose, NCC, derived from cellulose, the most abundant biopolymer, is one of the most promising materials. NCC has unique features, interesting for the development of new materials: the abundance of the source cellulose, its renewability and environmentally benign nature, its mechanical properties and its nano-scaled dimensions open a wide range of possible properties to be discovered. One of the most promising uses of NCC is in polymer matrix nanocomposites, because it can provide a significant reinforcement. This review provides an overview on this emerging nonmaterial, focusing on extraction procedures, especially from lignocellulosic biomass, and on technological developments and applications of NCC-based materials. Challenges and future opportunities of NCC-based materials will be are discussed as well as obstacles remaining for their large use. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:154 / 169
页数:16
相关论文
共 201 条
[1]   Glycerol eutectics as sustainable solvent systems [J].
Abbott, Andrew P. ;
Harris, Robert C. ;
Ryder, Karl S. ;
D'Agostino, Carmine ;
Gladden, Lynn F. ;
Mantle, Mick D. .
GREEN CHEMISTRY, 2011, 13 (01) :82-90
[2]   Novel solvent properties of choline chloride/urea mixtures [J].
Abbott, AP ;
Capper, G ;
Davies, DL ;
Rasheed, RK ;
Tambyrajah, V .
CHEMICAL COMMUNICATIONS, 2003, (01) :70-71
[3]  
Abdul K. H. P. S., 2012, CARBOHYD POLYM, V87, P963, DOI DOI 10.1016/J.CARBP0L.2011.08.078
[4]   Extraction of nanocellulose fibrils from lignocellulosic fibres: A novel approach [J].
Abraham, E. ;
Deepa, B. ;
Pothan, L. A. ;
Jacob, M. ;
Thomas, S. ;
Cvelbar, U. ;
Anandjiwala, R. .
CARBOHYDRATE POLYMERS, 2011, 86 (04) :1468-1475
[5]   (Bio)nanotechnologies to enhance environmental quality and energy production [J].
Alvarez, Luis H. ;
Cervantes, Francisco J. .
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2011, 86 (11) :1354-1363
[6]   Plasticized starch/tunicin whiskers nanocomposites.: 1.: Structural analysis [J].
Anglès, MN ;
Dufresne, A .
MACROMOLECULES, 2000, 33 (22) :8344-8353
[7]   Plasticized starch/tunicin whiskers nanocomposite materials.: 2.: Mechanical behavior [J].
Anglès, MN ;
Dufresne, A .
MACROMOLECULES, 2001, 34 (09) :2921-2931
[8]   Flow properties of microcrystalline cellulose suspension prepared by acid treatment of native cellulose [J].
Araki, J ;
Wada, M ;
Kuga, S ;
Okano, T .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1998, 142 (01) :75-82
[9]   Steric stabilization of a cellulose microcrystal suspension by poly(ethylene glycol) grafting [J].
Araki, J ;
Wada, M ;
Kuga, S .
LANGMUIR, 2001, 17 (01) :21-27
[10]  
Aramini A, 2000, EUR J ORG CHEM, V2000, P1793