Microstructure and magnetic properties of Al-doped barium ferrite with sodium citrate as chelate agent

被引：80

作者：

Chen, Daming ^{[1
]}

Liu, Yingli ^{[1
]}

Li, Yuanxun ^{[1
]}

Yang, Kai ^{[1
]}

Zhang, Huaiwu ^{[1
]}

机构：

[1] Univ Elect Sci & Technol China, State Key Lab Elect Films & Integrated Devices, Chengdu 610054, Peoples R China

来源：

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS | 2013年 / 337卷

基金：

中国国家自然科学基金;

关键词：

Magnetic material; Chemical synthesis; Magnetic property; X-ray diffraction topography; SITE PREFERENCE; HEXAFERRITE; NANOPARTICLES; HYSTERESIS; CO;

D O I：

10.1016/j.jmmm.2013.02.036

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

In this paper, M-type Al-doped barium ferrites were successfully synthesized using sodium citrate (SC) as the chelate agent by a chemical process complemented by a suitable thermal treatment of the precursor. It was found in TGA/DTA and XRD analysis that the crystallization and formation of single phase BaM had completed before 860 degrees C. The XRD data also confirmed Al substituting into Fe sites. Meanwhile, it can be seen from the SEM images that the particle size and morphology were not affected by Al doping. However, Al substitution played an important role on the magnetic properties. The saturation magnetization (M-s) of BaAlxFe12-xO19 decreased from 51.43 emu/g for the sample with x=0 to 28.32 emu/g at x=1.5. The anisotropy field (H-a), however, increased from 16.21 kOe to 25.01 kOe. In addition, M-s increased with enhancing the ratio of SC/Ba2+ (molar ratio), reaching a maximum when SC/Ba2+ was 13. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：65 / 69

页数：5

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