Ebonex supported iridium as anode catalyst for PEM water electrolysis

被引:31
|
作者
Slavcheva, Evelina [1 ]
Borisov, Galin [1 ]
Lefterova, Elefteria [1 ]
Petkucheva, Elitsa [1 ]
Boshnakova, Iveta [1 ]
机构
[1] Bulgarian Acad Sci, Acad Evgeni Budevski, Inst Electrochem & Energy Syst, BG-1040 Sofia, Bulgaria
关键词
Anode catalyst; Hydrogen generation; Iridium oxide; Ebonex; ELECTROCATALYTIC ACTIVITY; CHARGE-INJECTION; OXIDE-FILMS; ELECTRODES; PLATINUM; OXYGEN; ELECTROCHEMISTRY; DEPOSITION;
D O I
10.1016/j.ijhydene.2015.03.005
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The work presents a research on the preparation and properties of iridium dispersed on Magnelli phase titania by sol gel method. The material is characterised in regard to morphology, surface structure and electronic state, electrochemical performance, and catalytic activity toward the oxygen evolution reaction in view of its application as anode in polymer electrolyte membrane water electrolysis. The results obtained are discussed in comparison to the previously studied magnetron sputtered iridium oxide anodes. They show a need for improvements concerning the Ir/Ebonex active surface area and catalyst utilisation. At the same time, the performed accelerated durability tests demonstrate excellent stability of the synthesized composite catalyst and enhanced resistance to corrosion. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:11356 / 11361
页数:6
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