Effects of pretreatment factors on fermentable sugar production and enzymatic hydrolysis of mixed hardwood

被引:26
作者
Lim, Woo-Seok [1 ]
Lee, Jae-Won [1 ,2 ]
机构
[1] Chonnam Natl Univ, Dept Forest Prod & Technol, Program BK21, Kwangju 500757, South Korea
[2] Chonnam Natl Univ, Bioenergy Res Ctr, Kwangju 500757, South Korea
基金
新加坡国家研究基金会;
关键词
Pretreatment factor; Fermentable sugar; Enzymatic hydrolysis; Dicarboxylic acids; DILUTE-ACID PRETREATMENT; CORN STOVER; CELLULOSE HYDROLYSIS; SEVERITY; ETHANOL; HEMICELLULOSE; GLUCOSE; BIOMASS; SOLIDS; XYLAN;
D O I
10.1016/j.biortech.2012.11.122
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
The aim of this study was to investigate the effects of different acid catalysts and pretreatment factors on the hydrolysis of biomass compounds over a range of thermochemical pretreatments; maleic, oxalic, and sulfuric acids were each used under different pretreatment conditions. The most influential factor for fermentable sugar production in the dicarboxylic acid-pretreated mixed hardwood was pH. Reaction time was the next significant factor followed by reaction temperature. However, fermentable sugar production was more dependent on reaction temperature than time during sulfuric acid pretreatment, whereas the effect of acid concentration was considerably lower. Maleic acid pretreatment was very effective for attaining high glucose yields after enzymatic hydrolysis. The highest enzymatic hydrolysis yield was found following maleic acid pretreatment, which reached 95.56%. The trend in enzymatic hydrolysis yields that were detected concomitantly with pretreatment condition or type of acid catalyst was closely related to xylose production in the hydrolysate. Crown Copyright (C) 2012 Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:97 / 101
页数:5
相关论文
共 26 条
[1]   Elucidation of cellulose accessibility, hydrolysability and reactivity as the major limitations in the enzymatic hydrolysis of cellulose [J].
Bansal, Prabuddha ;
Vowell, Bryan J. ;
Hall, Melanie ;
Realff, Matthew J. ;
Lee, Jay H. ;
Bommarius, Andreas S. .
BIORESOURCE TECHNOLOGY, 2012, 107 :243-250
[2]   Influence of Xylan on the Enzymatic Hydrolysis of Steam-Pretreated Corn Stover and Hybrid Poplar [J].
Bura, Renata ;
Chandra, Richard ;
Saddler, Jack .
BIOTECHNOLOGY PROGRESS, 2009, 25 (02) :315-322
[3]   Conversion of olive tree biomass into fermentable sugars by dilute acid pretreatment and enzymatic saccharification [J].
Cara, Cristobal ;
Ruiz, Encarnacion ;
Oliva, Jose Miguel ;
Saez, Felicia ;
Castro, Eulogio .
BIORESOURCE TECHNOLOGY, 2008, 99 (06) :1869-1876
[4]   PRETREATMENT CATALYST EFFECTS AND THE COMBINED SEVERITY PARAMETER [J].
CHUM, HL ;
JOHNSON, DK ;
BLACK, SK ;
OVEREND, RP .
APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY, 1990, 24-5 :1-14
[5]   Biodegradation of Pinus radiata softwood by white- and brown-rot fungi [J].
Ferraz, A ;
Rodríguez, J ;
Freer, J ;
Baeza, J .
WORLD JOURNAL OF MICROBIOLOGY & BIOTECHNOLOGY, 2001, 17 (01) :31-34
[6]   Characterization of dilute acid pretreatment of silvergrass for ethanol production [J].
Guo, Gia-Luen ;
Chen, Wei-Hsi ;
Chen, Wen-Heng ;
Men, Lee-Chung ;
Hwang, Wen-Song .
BIORESOURCE TECHNOLOGY, 2008, 99 (14) :6046-6053
[7]   Complex xylo-oligosaccharides identified from hydrothermally treated Eucalyptus wood and brewery's spent grain [J].
Kabel, MA ;
Schols, HA ;
Voragen, AGJ .
CARBOHYDRATE POLYMERS, 2002, 50 (02) :191-200
[8]   Effect of pretreatment severity on xylan solubility and enzymatic breakdown of the remaining cellulose from wheat straw [J].
Kabel, Mirjam A. ;
Bos, Gijs ;
Zeevalking, Jan ;
Voragen, Alphons G. J. ;
Schols, Henk A. .
BIORESOURCE TECHNOLOGY, 2007, 98 (10) :2034-2042
[9]   Comparison of dilute mineral and organic acid pretreatment for enzymatic hydrolysis of wheat straw [J].
Kootstra, A. Maarten J. ;
Beeftink, Hendrik H. ;
Scott, Elinor L. ;
Sanders, Johan P. M. .
BIOCHEMICAL ENGINEERING JOURNAL, 2009, 46 (02) :126-131
[10]   Effect of Enzyme Supplementation at Moderate Cellulase Loadings on Initial Glucose and Xylose Release From Corn Stover Solids Pretreated by Leading Technologies [J].
Kumar, Rajeev ;
Wyman, C. E. .
BIOTECHNOLOGY AND BIOENGINEERING, 2009, 102 (02) :457-467