FT-IR and laser Raman spectroscopic investigation of the formation and stability of low temperature t-ZrO2

被引：48

作者：

Stefanic, G ^{[1
]}

Music, S ^{[1
]}

Popovic, S ^{[1
]}

Sekulic, A ^{[1
]}

机构：

[1] UNIV ZAGREB,FAC SCI,DEPT PHYS,ZAGREB 10001,CROATIA

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1997年 / 408卷

关键词：

t-ZrO2; m-ZrO2; FT-IR; Raman; XRD;

D O I：

10.1016/S0022-2860(96)09549-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The influence of the preparation chemistry on the formation and the stability of metastable t-ZrO2 was studied. gamma-Irradiation has very small (if any) influence on the r-ZrO2 --> m-ZrO2 transition, while increased temperature and pressure caused gradual transition of pure r-ZrO2 to m-ZrO2. Metastable t-ZrO2 containing SO42- impuirties proved to be more stable, and its transition was not uniform. The mentioned effects were monitored by FT-IR and laser Raman spectroscopy. X-ray diffraction was used as a complementary technique. (C) 1997 Elsevier Science B.V.

引用

页码：391 / 394

页数：4

共 6 条

[1]

BAILEY JE, 1972, BRIT CERAM TRANS J, V71, P25

[2] SULFATED ZIRCONIA CATALYSTS - THE CRYSTAL PHASES AND THEIR TRANSFORMATIONS [J].