[4-(2-Aminoethyl)morpholine-κ2 N,N′]aqua(oxalato-κ2 O,O′) copper(II) monohydrate

被引：0
|
作者：
Kocwin-Gielzak, K [1 ]
Marciniak, B [1 ]
机构：
[1] Jan Dlugosz Univ, Inst Chem & Environm Protect, PL-42200 Czestochowa, Poland
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷
关键词：
D O I：
10.1107/S1600536805042091
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The crystal structure of the title compound, [Cu(C2O4)(C6H14N2O)(H2O)] center dot H2O, includes a CuN2O3 coordination polyhedron in the shape of a slightly distorted square pyramid with bidentate morpholine and oxalate ligands. Copper(II) is coordinated by 4-(2-aminoethyl) morpholine (etMorph) N atoms, with Cu-N distances of 2.050 (3) and 1.985 (3) angstrom, and two carboxylate O atoms from the oxalate ligand, with Cu-O distances of 1.955 (2) and 1.965 ( 2) angstrom; both ligands are located in the basal plane, whereas a water molecule is apically positioned [Cu-O = 2.251 (3) angstrom]. The crystal packing is dominated by N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds.
引用
收藏
页码：M155 / M157
页数：3
相关论文
共 50 条
  • [31] catena-Poly[[(2,2′-bipyridine-κ2N,N′)cobalt(II)]-μ-oxalato-κ4O1,O2:O1′,O2′]
    Chang, Yan
    Zhang, Kou-Lin
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1243 - +
  • [32] Aqua(2-ethylpyridine-N)(N-salicylideneglycinato-O, N, O′)copper(II)
    Warda, SA
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1998, 54 : 1236 - 1238
  • [33] (Acetato-O,O')[tris(2-aminoethyl)amine-N,N',N'',N''']nickel(II) perchlorate
    Fun, HK
    Yip, BC
    Lu, ZL
    Duan, CY
    Tian, YP
    You, XZ
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 : 509 - 512
  • [34] μ-Oxalato-κ4O1,O2:O1′,O2′-bis{[N,N′-bis(pyridin-2-ylmethylene)propane-1,2-diamine-κ4-N,N′,N",N"′]copper(II)} bis(perchlorate)
    Liu, Tian-Fu
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M1856 - M1858
  • [35] μ-oxalato-κ4O1,O2:O1′,O2′-bis[aqua(diethylene-triamine-κ3N)nickel(II)] bis(tetraphenylborate)
    Callejo, LM
    Muga, I
    Vitoria, P
    Reinoso, S
    Román, P
    Gutiérrez-Zorrilla, JM
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : M684 - M686
  • [36] [4-(2-Aminoethyl)piperazin-1-ium]trichloridocopper(II) monohydrate
    Ikram, Baccar
    Fatma, Zouari
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1539 - U399
  • [37] μ-Oxalato-k4O1,O2:O1′,O2′-bis[aqua(2,2′-bipyridyl-k2N, N′)copper(II)] bis(hydrogen squarate)
    Reinoso, S
    Vitoria, P
    San Felices, L
    Lezama, L
    Gutiérrez-Zorrilla, JM
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2005, 61 : M1677 - M1679
  • [38] Investigation on the physicochemical properties of bis[4-(2-aminoethyl) morpholine-K2 N, N'] diaquanickel (II) dichloride NLO-single crystal
    Chidambaranathan, B.
    Sivaraj, S.
    Vijayamathubalan, P.
    Rajasekar, S. Abraham
    Sagayaraj, P.
    Selvakumar, S.
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2024, 35 (29)
  • [39] Bis[(R)-1-phenylethylaminium]μ-oxalato-κ4O,O′:O"O′"-bis[diaqua(oxalato-κ2O,O′)cobaltate(II)]
    Yang, Xin
    Li, Jiang
    Wang, Hai-Wen
    Zhao, Xin-Hua
    Shan, Yong-Kui
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M1554 - U88
  • [40] Aqua(2-ethylpyridine-N)(N-salicylideneglycinato-O,N,O prime )copper(II)
    Acta Crystallogr Sect C Cryst Struct Commun, pt 9 (1236-1238):
12345