Thermal stability of In2(MoO4)3 and phase equilibria in the MoO3-In2O3 system

被引：15

作者：

Filipek, E. ^{[1
]}

Rychlowska-Himmel, I. ^{[1
]}

Paczesna, A. ^{[1
]}

机构：

[1] W Pomeranian Univ Technol, Fac Chem Technol & Engn, Dept Inorgan & Analyt Chem, PL-71065 Szczecin, Poland

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2012年 / 109卷 / 02期

关键词：

Indium(III) molybdate(VI); MoO3-In2O3; system; DTA/TG; Thermal decomposition; XRD; SOLID-STATE; AMBIENT-PRESSURE; O SYSTEM; IN2O3; MOLYBDATES;

D O I：

10.1007/s10973-012-2224-7

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Thermal stability of a compound forming in a binary system MoO3-In2O3 was investigated by DTA/TG, XRD and SEM methods in this study. For the first time, the diagram of phase equilibria established in the whole range of concentrations of this system's components has been constructed. The temperature and concentration ranges of the components of MoO3-In2O3 system in which the compound In-2(MoO4)(3) co-exists in solid state with MoO3 or In2O3 or with the liquid were determined. The composition and melting point of the eutectic mixture consisting of In-2(MoO4)(3) and MoO3 were found.

引用

页码：711 / 716

页数：6

共 26 条

[11] Photochromism of molybdenum oxide [J].

He, T ;

Yao, JN .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2003, 4 (02) :125-143

[12]

Klevtsov PW, 1968, IAN SSSR NEORG MATER, V4, P345

[13] Phase transition and vibrational properties of A2(BO4)3 compounds (A=Sc, In; B=Mo, W) [J].

Maczka, M ;

Hermanowicz, K ;

Hanuza, J .

JOURNAL OF MOLECULAR STRUCTURE, 2005, 744 :283-288

[14] In2Mo3O12: A low negative thermal expansion compound [J].

Marinkovic, Bojan A. ;

Ari, Monica ;

Jardim, Paula Mendes ;

de Avillez, Roberto R. ;

Rizzo, Fernando ;

Ferreira, Fabio Furlan .

THERMOCHIMICA ACTA, 2010, 499 (1-2) :48-53

[15] A COMPREHENSIVE STUDY OF TRIVALENT TUNGSTATES AND MOLYBDATES OF TYPE L2(MO4)3 [J].

NASSAU, K ;

LEVINSTEIN, HJ ;

LOIACONO, GM .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1965, 26 (12) :1805-+

[16] Mechanism of interaction of BaO and MoO3 in a combustion wave [J].

Postnikov, AY ;

Gavrilov, PI ;

Tarasova, AI .

COMBUSTION EXPLOSION AND SHOCK WAVES, 1999, 35 (05) :514-517

[17] Phase equilibria in the system Rb3PO4-Ba3(PO4)2 [J].

Radominska, E. ;

Znamierowska, T. ;

Szuszkiewicz, W. .

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2011, 103 (02) :761-766

[18] THERMODYNAMIC INVESTIGATION OF THE VAPORIZATION OF MOLYBDENUM TRIOXIDE [J].

SAMANT, MS ;

KERKAR, AS ;

BHARADWAJ, SR ;

DHARWADKAR, SR .

JOURNAL OF ALLOYS AND COMPOUNDS, 1992, 187 (02) :373-379

[19]

Solov'eva A.E., 1987, Refractories and Industrial Ceramics, V28, P380, DOI DOI 10.1007/BF01400027

[20] Chemical vapor transport of ternary indium molybdates [J].

Steiner, U ;

Reichelt, W .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2005, 631 (10) :1877-1884

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