Preparation of La-B-TiO2 Photocatalyst by Sol-Gel and Solvothermal Methods

被引:1
作者
Zhang, Wenjie [1 ]
Hu, Tingting [1 ]
机构
[1] Shenyang Ligong Univ, Sch Environm & Chem Engn, Shenyang 110159, Peoples R China
基金
中国国家自然科学基金;
关键词
TiO2; Photocatalysis; Doping; Sol-gel; Solvothermal; N-DOPED TIO2; VISIBLE-LIGHT; LANTHANUM;
D O I
10.14233/ajchem.2013.14991
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
La-TiO2, B-TiO2 and La-B-TiO2 photocatalysts were prepared by sol-gel method. The La-TiO2 containing 0.5 % La presented the maximum photocatalytic activity of 35.4 %. The sample doped with 3 % boron showed the optimum photocatalytic activity. When La content was below 3 %, degradation rate on La-3 % B-TiO2 was nearly constant around 30 %. However, degradation rate dropped drastically on the sample containing 5 % La. La-B-TiO2 photocatalysts were prepared by solvothermal method. The results indicated that the total volume of N-2 adsorbed on 1 % La-3 % B-TiO2 increased with the increase of relative pressure P/P-o. The average pore size of the material was 16.29 nm and the total pore volume was 0.412 mL/g. Specific surface area of the material was 101.45 m(2)/g. When La content was 0.5 %, methyl orange adsorption rate on the material 0.5 % La-3 % B-TiO2 was less than 5 % and photocatalytic degradation rate was 39.9 %.
引用
收藏
页码:9069 / 9072
页数:4
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