Polymeric spin transition compounds: EXAFS and thermal behaviour

被引：19

作者：

Michalowicz, A ^{[1
]}

Moscovici, J

Garcia, Y

Kahn, O

机构：

[1] Univ Paris 12, GPMD, F-94010 Creteil, France

[2] CNRS, UPR 9046, INst Chim Mat Condensee Bordeaux, LSM, F-33608 Pessac, France

来源：

JOURNAL OF SYNCHROTRON RADIATION | 1999年 / 6卷

关键词：

inorganic polymers; spin transition; EXAFS structure; multiple scattering;

D O I：

10.1107/S090904959900093X

中图分类号：

TH7 [仪器、仪表];

学科分类号：

0804 ; 080401 ; 081102 ;

摘要：

The structures of large thermal hysteresis Fe(II) polymeric spin transition compounds have been studied by EXAFS. The assumption that a peak at 7 Angstrom can be assigned to a multiple scattering double metal-metal distance in an aligned polymeric structure is confirmed. For the first time, such an aligned structure was observed on High Spin (HS) compound of the family. A qualitative study of the thermal variation of this multiple scattering peak was performed. The correlation between this thermal behaviour. due to variations in the vibrational entropy, and the electronic structure of the metallic ions is discussed.

引用

页码：231 / 232

页数：2