Effect of some ethoxylated fatty acids on the corrosion behaviour of mild steel in sulphuric acid solution

被引:107
作者
El Sherbini, EEF [1 ]
机构
[1] Ain Shams Univ, Fac Sci, Dept Chem, Cairo, Egypt
关键词
fatty acids; mild steel corrosion; inhibition;
D O I
10.1016/S0254-0584(99)00093-0
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The inhibition of the corrosion of mild steel in 1.0 M sulphuric acid solution by some ethoxylated fatty acids OL[E)](20), OL[EO](40) and OL[EO](80) has been studied in relation to the concentration of the inhibitors as well as the temperature using chemical (weight loss) and electrochemical (potentiodynamic polarization) techniques. The inhibition efficiency increases with increasing the concentration and the chain length of the inhibitor but decreases with temperature. The inhibition was assumed to occur via adsorption of the fatty acid molecules on the metal surface. The thermodynamic functions of dissolution and adsorption processes were calculated. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:286 / 290
页数:5
相关论文
共 21 条
  • [11] HACKERMAN N, 1962, CORROSION, V18, P37
  • [12] HOAR TP, 1960, P 1 EUR S CORR INH F, V73
  • [13] 5-amino- and 5-chloro-indole as mild steel corrosion inhibitors in 1n sulphuric acid
    Moretti, G
    Quartarone, G
    Tassan, A
    Zingales, A
    [J]. ELECTROCHIMICA ACTA, 1996, 41 (13) : 1971 - 1980
  • [14] EFFECT OF SOME HYDRAZINE DERIVATIVES ON CORROSION OF AL IN HCL SOLUTION
    MOUSSA, MNH
    TAHA, FIM
    GOUDA, MMA
    SINGAB, GM
    [J]. CORROSION SCIENCE, 1976, 16 (06) : 379 - 385
  • [15] Oakes G., 1969, BRIT CORROS J, V4, P66
  • [16] The effect of same ethoxylated fatty acids on corrosion of aluminium in hydrochloric acid solutions
    Osman, MM
    El Rehim, SSA
    [J]. MATERIALS CHEMISTRY AND PHYSICS, 1998, 53 (01) : 34 - 40
  • [17] RENGAMANI S, 1994, J APPL ELECTROCHEM, V24, P355, DOI 10.1007/BF00242066
  • [18] APPLICATION OF INHIBITORS FOR ACID-MEDIA - REPORT PREPARED FOR THE EUROPEAN-FEDERATION-OF-CORROSION WORKING PARTY ON INHIBITORS
    SCHMITT, G
    [J]. BRITISH CORROSION JOURNAL, 1984, 19 (04): : 165 - 176
  • [19] SHALABY MN, 1996, THESIS AM SHAMS U
  • [20] Sykes J. W., 1990, British Corrosion Journal, V25, P175