Kinetics of N-ethylcarbazole hydrogenation over a supported Ru catalyst for hydrogen storage

被引：63

作者：

Wan, Chao ^{[1
]}

An, Yue ^{[1
]}

Chen, Fengqiu ^{[1
]}

Cheng, Dangguo ^{[1
]}

Wu, Fuying ^{[1
]}

Xu, Guohua ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem & Biol Engn, Hangzhou 310027, Zhejiang, Peoples R China

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2013年 / 38卷 / 17期

关键词：

N-ethylcarbazole; Catalytic hydrogenation; Ru/gamma-Al2O3; Kinetics; RUTHENIUM; DECALIN; RELEASE;

D O I：

10.1016/j.ijhydene.2013.04.022

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The hydrogenation kinetics of N-ethylcarbazole over Ru/gamma-Al2O3 was investigated to find the rate of controlling step on the mass transfer-reaction processes. The results showed that the kinetics of reaction was controlled by the hydrogenation reaction on the catalyst surfaces. This reaction followed first-order kinetics with an apparent activation energy of 30.94 kJ/mol. The apparent kinetics model of the hydrogenation was established. Copyright (c) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：7065 / 7069

页数：5

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