Green Synthesis of Graphene

被引:170
作者
Kartick, B. [1 ]
Srivastava, S. K. [1 ]
Srivastava, I. [2 ]
机构
[1] Indian Inst Technol, Dept Chem, Kharagpur 721302, W Bengal, India
[2] Bengal Engn & Sci Univ, Dept Met & Mat Engn, Howrah 711103, India
关键词
Graphene; Synthesis; Green Route; Cocos nucifera L; AFM; GRAPHITE OXIDE; REDUCED GRAPHENE; REDUCTION; CARBON; ROUTE; DISPERSIONS; NANOSHEETS;
D O I
10.1166/jnn.2013.7461
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The present work reports a green route to synthesis of graphene by reduction of graphite oxide with cocos nucifera L. (coconut water) as reducing agent which is naturally available, non-toxic and environmental friendly. The graphite oxide has been prepared by oxidation of graphite with KCIO3/NaNO3/H2SO4 as reported in our earlier findings. X-ray diffraction, FTIR, UV-Visible and Raman spectroscopy confirmed the formation of graphene. SEM, TEM and AFM analyses have also been carried out to study the morphological characteristics of the obtained product. Also, TG analysis presents the thermal stability behavior of the formed product. Zeta potential measurements were also carried out to determine the surface charge characteristics.
引用
收藏
页码:4320 / 4324
页数:5
相关论文
共 38 条
[1]   Honeycomb Carbon: A Review of Graphene [J].
Allen, Matthew J. ;
Tung, Vincent C. ;
Kaner, Richard B. .
CHEMICAL REVIEWS, 2010, 110 (01) :132-145
[2]   Epitaxial Graphene Growth on α-SiC: Probing the Effect of Surface Orientation [J].
Camara, N. ;
Jouault, B. ;
Caboni, A. ;
Tiberj, A. ;
Godignon, P. ;
Camassel, J. .
NANOSCIENCE AND NANOTECHNOLOGY LETTERS, 2011, 3 (01) :49-54
[3]   Few-Layer Graphene Direct Deposition on Ni and Cu Foil by Cold-Wall Chemical Vapor Deposition [J].
Chang, Q. H. ;
Guo, G. L. ;
Wang, T. ;
Ji, L. C. ;
Huang, L. ;
Ling, B. ;
Yang, H. F. .
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2012, 12 (08) :6516-6520
[4]   A rapid room temperature chemical route for the synthesis of graphene: metal-mediated reduction of graphene oxide [J].
Dey, Ramendra Sundar ;
Hajra, Saumen ;
Sahu, Ranjan K. ;
Raj, C. Retna ;
Panigrahi, M. K. .
CHEMICAL COMMUNICATIONS, 2012, 48 (12) :1787-1789
[5]   Deoxygenation of Exfoliated Graphite Oxide under Alkaline Conditions: A Green Route to Graphene Preparation [J].
Fan, Xiaobin ;
Peng, Wenchao ;
Li, Yang ;
Li, Xianyu ;
Wang, Shulan ;
Zhang, Guoliang ;
Zhang, Fengbao .
ADVANCED MATERIALS, 2008, 20 (23) :4490-4493
[6]   Facile Synthesis of Graphene Nanosheets via Fe Reduction of Exfoliated Graphite Oxide [J].
Fan, Zhuang-Jun ;
Kai, Wang ;
Yan, Jun ;
Wei, Tong ;
Zhi, Lin-Jie ;
Feng, Jing ;
Ren, Yue-ming ;
Song, Li-Ping ;
Wei, Fei .
ACS NANO, 2011, 5 (01) :191-198
[7]   Coconut water (Cocos nucifera L.)-A new biocatalyst system for organic synthesis [J].
Fonseca, Aluisio M. ;
Monte, Francisco Jose Q. ;
de Oliveira, Maria da Conceicao F. ;
de Mattos, Marcos C. ;
Cordell, Geoffrey A. ;
Braz Filho, Raimundo ;
Lemos, Telma L. G. .
JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC, 2009, 57 (1-4) :78-82
[8]   Surface Modification of Graphene Nanosheets with Gold Nanoparticles: The Role of Oxygen Moieties at Graphene Surface on Gold Nucleation and Growth [J].
Goncalves, Gil ;
Marques, Paula A. A. P. ;
Granadeiro, Carlos M. ;
Nogueira, Helena I. S. ;
Singh, M. K. ;
Gracio, J. .
CHEMISTRY OF MATERIALS, 2009, 21 (20) :4796-4802
[9]  
Hennig G.R., 1959, Progress in Inorganic Chemistry, V1, P125, DOI [DOI 10.1002/9780470166024.CH2, 10.1002/9780470166024.ch2]
[10]   Preparation of Gold Nanoparticle/Graphene Composites with Controlled Weight Contents and Their Application in Biosensors [J].
Hong, Wenjing ;
Bai, Hua ;
Xu, Yuxi ;
Yao, Zhiyi ;
Gu, Zhongze ;
Shi, Gaoquan .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (04) :1822-1826