Study of the chemiluminescent characteristics of ninhydrin and its application

被引：9

作者：

Chen, GN

Xu, XQ

Zhang, F

机构：

[1] Department of Chemistry, Fuzhou University, Fuzhou, Fujian

来源：

ANALYST | 1996年 / 121卷 / 01期

关键词：

ninhydrin; chemiluminescence; amino acid; flow injection;

D O I：

10.1039/an9962100037

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Ninhydrin was found to exhibit chemiluminescence (CL) when it was oxidized with hydrogen peroxide in neutral or weakly acidic solution. Copper(II) and Co-II can catalyse the CL reaction, on the basis of which ppb levels of Cu-II and Co-II can be determined. In the presence of Cu-II, some amino acids enhanced the CL reaction, whereas others inhibited the CL reaction in the presence of Co-II. A flow-injection system with CL detection was developed for the determination of some amino acids. The mechanism of the CL reaction is discussed.

引用

页码：37 / 41

页数：5