DNA-Assisted β-phase Nucleation and Alignment of Molecular Dipoles in PVDF Film: A Realization of Self-Poled Bioinspired Flexible Polymer Nanogenerator for Portable Electronic Devices

被引:157
作者
Tamang, Abiral [1 ]
Ghosh, Sujoy Kumar [1 ]
Garain, Samiran [1 ]
Alam, Md. Mehebub [1 ]
Haeberle, Joerg [2 ]
Henkel, Karsten [2 ]
Schmeisser, Dieter [2 ]
Mandal, Dipankar [1 ]
机构
[1] Jadavpur Univ, Dept Phys, Organ Nanopiezoelect Device Lab, Kolkata 700032, India
[2] Brandenburg Tech Univ Cottbus Senftenberg, Angew Phys Sensor, D-03046 Cottbus, Germany
关键词
PVDF; beta-phase; DNA; self-poling; piezoelectric flexible nanogenerator; ENERGY; PERFORMANCE; NANOPARTICLES; NANOWIRES; COMPOSITE;
D O I
10.1021/acsami.5b04161
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A flexible nanogenerator (NG) is fabricated with a poly(vinylidene fluoride) (PVDF) film, where deoxyribonucleic acid (DNA) is the agent for the electroactive beta-phase nucleation. Denatured DNA is co-operating to align the molecular -CH2/-CF2 dipoles of PVDF causing piezoelectricity without electrical poling. The NG is capable of harvesting energy from a variety of easily accessible mechanical stress such as human touch, machine vibration, football juggling, and walking. The NG exhibits high piezoelectric energy conversion efficiency facilitating the instant turn-on of several green or blue light-emitting diodes. The generated energy can be used to charge capacitors providing a wide scope for the design of self-powered portable devices.
引用
收藏
页码:16143 / 16147
页数:5
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