Preparation and characterization of N-alkyl-Se-alkylselenocarbamates

被引：19

作者：

Koketsu, M ^{[1
]}

Ishida, M ^{[1
]}

Takakura, N ^{[1
]}

Ishihara, H ^{[1
]}

机构：

[1] Gifu Univ, Fac Engn, Dept Chem, Gifu 5011193, Japan

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 67卷 / 02期

关键词：

D O I：

10.1021/jo010763k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several N-alkyl-Se-alkylselenocarbamates were prepared. The structure was confirmed by X-ray diffraction. N-Alkyl-Se-alkylselenocarbamates showed interesting NMR spectral features in C-13 and Se-77 NMR. They could be explained by the equilibrium between the major s-trans and the minor s-cis forms. This assumption was confirmed by the theoretical calculations.

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页码：486 / 490

页数：5

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