Iron-Catalyzed Aerobic Oxidation of Allylic Alcohols: The Issue of C=C Bond Isomerization

被引：66

作者：

Liu, Jinxian ^{[1
,2
]}

Ma, Shengming ^{[1
,3
]}

机构：

[1] E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China

[2] Longyan Univ, Coll Chem & Mat Sci, Longyan 364000, Peoples R China

[3] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

ORGANIC LETTERS | 2013年 / 15卷 / 20期

关键词：

DIARYLPROLINOL SILYL ETHER; BAYLIS-HILLMAN REACTION; PROPARGYLIC ALCOHOLS; SELECTIVE OXIDATION; CARBONYL-COMPOUNDS; ALDOL REACTION; ALPHA; BETA-UNSATURATED ALDEHYDES; UNSATURATED ALDEHYDES; MICHAEL ADDITION; FACILE SYNTHESIS;

D O I：

10.1021/ol402434x

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An aerobic oxidation of allylic alcohols using Fe(NO3)(3)center dot 9H(2)O/TEMPO/NaCl as catalysts under atmospheric pressure of oxygen at room temperature was developed. This eco-friendly and mild protocol provides a convenient pathway to the synthesis of stereodefined alpha,beta-unsaturated enals or enones with the retention of the C-C double-bond configuration.

引用

页码：5150 / 5153

页数：4

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