Silica-alumina catalytic materials: A critical review

被引：66
作者：
Busca, Guido [1 ]
机构：
[1] Univ Genoa, Dipartimento Ingn Civile Chim & Ambientale DICCA, Via Opera Pia 15, I-16145 Genoa, Italy
来源：
CATALYSIS TODAY | 2020年 / 357卷
关键词：
Silica-aluminas; Bronsted acidity; Lewis acidity; Amorphous catalyst; Support for catalysts; Tuning acidity; BRONSTED ACID SITES; SKELETAL ISOMERIZATION; SURFACE-ACIDITY; ACTIVE-SITES; FT-IR; SPECTROSCOPIC CHARACTERIZATION; PENTACOORDINATED ALUMINUM; STUFFED DERIVATIVES; FCC GASOLINE; DEHYDRATION;
D O I：
10.1016/j.cattod.2019.05.011
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The applications of silica-aluminas in industrial catalytic processes are briefly reviewed. The literature data on the surface chemistry and structural chemistry of silica-aluminas are summarized. The Al-stuffed amorphous silica model is proposed for fully amorphous materials, and described. The reasons for the versatility of these materials as acid or acido-basic catalysts as well as tunable supports for metal and sulphide catalysts are also discussed.
引用
收藏
页码：621 / 629
页数：9
相关论文
共 159 条
[91]  
LUSSIEN RJ, 1976, Patent No. 3974099
[92]   NUCLEAR-MAGNETIC-RESONANCE STUDY OF THE DEALUMINATION OF AN AMORPHOUS SILICA-ALUMINA CATALYST [J].
MAN, PP ;
PELTRE, MJ ;
BARTHOMEUF, D .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1990, 86 (09) :1599-1602
[93]   A statistical approach to control porosity in silica-doped alumina supports [J].
Mardkhe, Maryam Khosrayi ;
Lawson, John ;
Huang, Baiyu ;
Handly, Erika D. ;
Woodfield, Brian F. .
MICROPOROUS AND MESOPOROUS MATERIALS, 2015, 210 :116-124
[94]   Extrudate versus Powder Silica Alumina as Support for Re2O7 Catalyst in the Metathesis of Seed Oil-Derivatives - A Comparison [J].
Marvey, Bassie B. .
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2009, 10 (01) :213-220
[95]   Selective ring opening of naphthenic molecules [J].
McVicker, GB ;
Daage, M ;
Touvelle, MS ;
Hudson, CW ;
Klein, DP ;
Baird, WC ;
Cook, BR ;
Chen, JG ;
Hantzer, S ;
Vaughan, DEW ;
Ellis, ES ;
Feeley, OC .
JOURNAL OF CATALYSIS, 2002, 210 (01) :137-148
[96]   PRODUCT DISTRIBUTIONS IN DEHYDROCHLORINATION OF SOME CHLOROALKANES OVER ALUMINA, SILICA-ALUMINA, AND POTASSIUM HYDROXIDE SILICA GEL [J].
MOCHIDA, I ;
UCHINO, A ;
FUJITSU, H ;
TAKESHITA, K .
JOURNAL OF CATALYSIS, 1976, 43 (1-3) :264-272
[97]   Particular selectivity of m-xylene isomerization over MCM-41 mesoporous aluminosilicates [J].
Morin, S ;
Ayrault, P ;
ElMouahid, S ;
Gnep, NS ;
Guisnet, M .
APPLIED CATALYSIS A-GENERAL, 1997, 159 (1-2) :317-331
[98]   Bio-Ethanol Based Ethylene [J].
Morschbacker, Antonio .
POLYMER REVIEWS, 2009, 49 (02) :79-84
[99]   Highly Dispersed SiOx/Al2O3 Catalysts Illuminate the Reactivity of Isolated Silanol Sites [J].
Mouat, Aidan R. ;
George, Cassandra ;
Kobayashi, Takeshi ;
Pruski, Marek ;
van Duyne, Richard P. ;
Marks, Tobin J. ;
Stair, Peter C. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (45) :13346-13351
[100]   Amorphous silica-alumina - perspective supports for selective hydrotreating of FCC gasoline: Influence of Mg [J].
Nadeina, K. A. ;
Klimov, O. V. ;
Danilova, I. G. ;
Pereyma, V. Yu. ;
Gerasimov, E. Yu. ;
Prosvirin, I. P. ;
Noskov, A. S. .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2018, 223 :22-35
567891011121314