Crystal structure of a tantal cluster with tetraphenylborate-anion: [Ta6Br12(H2O)6](BPh4)2•4H2O

被引：3

作者：

Anyushin, A. V. ^{[1
,2
]}

Sokolov, M. N. ^{[1
,2
]}

Peresypkina, E. V. ^{[1
]}

Fedin, V. P. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk, Russia

[2] Novosibirsk State Univ, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2013年 / 54卷 / 02期

关键词：

tantalum; bromine; cluster; X-ray structure; hydrogen bonds; HALIDE CLUSTERS; BROMIDE; CHEMISTRY; NIOBIUM;

D O I：

10.1134/S0022476613020261

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of the [Ta6Br12(H2O)(6)](BPh4)(2)center dot 4H(2)O salt (1), obtained from Ta6Br14 center dot 7H(2)O and NaBPh4, is determined by X-ray crystallographic analysis. The structure contains a network of hydrogen bonds, which organizes the cluster cations into layers.

引用

页码：454 / 458

页数：5

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