Synthesis and Structure of Perovskite ScMnO3

被引：22

作者：

Chen, Haiyan ^{[1
]}

Yu, Tian ^{[1
]}

Gao, Peng ^{[1
]}

Bai, Jianming ^{[2
]}

Tao, Jing ^{[3
]}

Tyson, Trevor A. ^{[1
]}

Wang, Liping ^{[4
]}

Lalancette, Roger ^{[5
]}

机构：

[1] New Jersey Inst Technol, Dept Phys, Newark, NJ 07102 USA

[2] Brookhaven Natl Lab, Natl Synchrotron Light Sources, Upton, NY 11973 USA

[3] Brookhaven Natl Lab, Condensed Matter Phys & Mat Sci Dept, Upton, NY 11973 USA

[4] SUNY Stony Brook, Inst Mineral Phys, Stony Brook, NY 11794 USA

[5] Rutgers State Univ, Dept Chem, Newark, NJ 07102 USA

来源：

INORGANIC CHEMISTRY | 2013年 / 52卷 / 16期

关键词：

CRYSTAL;

D O I：

10.1021/ic4016838

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The rare-earth manganites RMnO3 (R = rare earth) are a class of important multiferroics with stable hexagonal structures for small R ion radius (Sc, Lu, Yb, ...). Metastable perovskite phases of these systems possess intriguing electronically driven electrical polarization, but the synthesis of the perovskite phase for the end member ScMnO3 system has proven to be elusive. We report the structure of a new monoclinic P2(1)/n perovskite phase of ScMnO3 synthesized from the hexagonal phase under high-pressure and high-temperature conditions. This extends the small ion region for so-called E-phase electronically driven ferroelectric manganese perovsites.

引用

页码：9692 / 9697

页数：6

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