Metal complexas of biologically important ligands.: CXL.: Halfsandwich complexes of ruthenium(II), rhodium(III), iridium(III) and palladium(II), platinum(II) complexes with N,O-chelates of fluorine and thiophene containing α-amino acids

被引:0
|
作者
Koch, D [1 ]
Beck, W [1 ]
机构
[1] Univ Munich, Dept Chem, D-81377 Munich, Germany
关键词
2-fluorophenyl glycine and alanine; 2-thienyl glycine and alanine; ruthenium;
D O I
暂无
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
o-Fluorophenyl glycine and alanine, 2-thienyl glycine and alanine form with dinuclear, chloro bridged metal complexes the chiral N,O-chelates (arene)M(Cl)(NH2CHRCO2) (M = Ru, Rh, Ir; arene = cymene, Cp*) and (R3P)(Cl)M(NH2CHRCO2) (M = Pd, Pt) as mixtures of diastereoisomers or cis/trans-isomers, respectively.
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页码:1271 / 1280
页数:10
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