Heat Capacity Close to the Unattainable Critical Layering Point

被引：6

作者：

Chaban, I. A. ^{[1
]}

Rodnikova, M. N. ^{[2
]}

机构：

[1] Russian Acad Sci, NN Andreev Acoust Inst, Moscow 117036, Russia

[2] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 117907, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2008年 / 82卷 / 12期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1134/S003602440812008X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An analysis of the literature data on the heat capacity of aqueous low-concentration solutions of tert-butanol at several temperatures showed that the heat capacity peak in this concentration region was largely related to critical concentration fluctuations close to the binodal, which appeared because of microlayering on the network of H-bonds in solutions of hydrophobic nonelectrolyte molecules.

引用

页码：2019 / 2024

页数：6

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