An ansa-Heteroborabenzene Divalent Lanthanide Amide through C-H Bond Cleavage

被引：42

作者：

Cui, Peng ^{[1
]}

Chen, Yaofeng ^{[1
]}

Li, Guangyu ^{[1
]}

Xia, Wei ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 51期

基金：

中国国家自然科学基金;

关键词：

amides; boron; bridging ligands; heterocycles; lanthanides;

D O I：

10.1002/anie.200803581

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bridging is the ansa: Both neutral borabenzene and anionic boratabenzene coordinate to a lanthanide ion in an ansaborabenzene divalent lanthanide amide (see picture). The complex, which was synthesized through an unexpected C-H bond cleavage, displays notable structural features, and is potentially reactive, as demonstrated by the insertion reaction of a carbodiimide into the metal-nitrogen bond. (Figure Presented).

引用

收藏

页码：9944 / 9947

页数：4

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