[Fe-2(CO)(4)(PMe(3))(4)(mu-H)(mu-SiCl2)][Fe(CO)(4)(SiCl3)]

被引:4
|
作者
Simons, RS
Tessier, CA
机构
[1] Univ of Akron, Akron
关键词
D O I
10.1107/S0108270195013825
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The structure of tetracarbonyl-mu-(dichlorosilylene)-mu-hydrido-tetrakis(trimethylphosphine)diiron(1+) tetracarbonyl(trichlorosilyl)ferrate(1-), has been determined at 119 K. The cation has an Fe-Fe distance of 2.947 (2) Angstrom and an average Fe-Si distance of 2.249 (3) Angstrom. A bridging hydride was located from a difference map with Fe-H distances of 1.77 and 1.63 Angstrom. The anion has an Fe-Si distance of 2.238 (3) Angstrom.
引用
收藏
页码:840 / 842
页数:3
相关论文
共 50 条