Microstructural investigation of the oxide scale on Zr-2.5Nb and its interface with the alloy substrate

Oxidized Zr-2.5Nb is being developed as an articular bearing surface for the femoral component in total joint arthroplasty. It has so far demonstrated superior wear performance against ultrahigh molecular weight polyethylene (UHMWPE) with respect to traditional articulating materials such as Co-Cr-Mo alloys. In this investigation, we used thermogravimetric analysis, transmission electron microscopy, and in situ x-ray diffraction techniques to study the microstructure and stress state of the oxide scale grown on Zr-2.5Nb. The oxidation temperature not only determines the kinetics of oxidation but the morphology of the various oxidation products. We have identified the oxidation products of both phases of the two phase alloy and correlated them with the original alloy microstructure. These include not only monoclinic zirconia but also small amounts of tetragonal zirconia and a mixed oxide phase combining both zirconium and niobium. The alloy microstructure both influences the final oxidation products and is reflected in the microstructure of the oxide. The oxide scale itself has a predominantly columnar microstructure which extends from the oxide/metal interface to the outer surface of the oxide. In situ. x-ray diffraction measurements revealed that the oxide scale is stressed in compression following cooling and exhibits strong crystallographic texture. The oxide/metal interface is continuous, without pores or voids which might be detrimental to oxide adhesion. In addition, we have identified a phase which develops at the interface between the beta-zirconium grains and the oxide. We have also identified amorphous regions within the oxide scale which serve as sinks for silicon and other impurity elements found in the alloy.