Reductive Coupling of Carbon Dioxide and an Aldehyde Mediated by a Copper(I) Complex toward the Synthesis of α-Hydroxycarboxylic Acids

被引：14

作者：

Masada, Koichiro ^{[1
]}

Kusumoto, Shuhei ^{[1
]}

Nozaki, Kyoko ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Engn, Dept Chem & Biotechnol, Bunkyo Ku, Tokyo 1138656, Japan

来源：

ORGANIC LETTERS | 2020年 / 22卷 / 13期

关键词：

METAL-CATALYZED CARBOXYLATION; C-H CARBOXYLATION; HOMOGENEOUS HYDROGENATION; DIARYL KETONES; FORMIC-ACID; CO2; ARYL; EPOXIDES; BONDS; COPOLYMERIZATION;

D O I：

10.1021/acs.orglett.0c00995

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Copper-mediated reductive coupling between CO2 and an aldehyde to form alpha-hydroxycarboxylic acid was achieved using silylborane as a reductant. CO2 cleanly inserted into a copper-carbon bond that was formed by the reaction between a silylcopper-NHC complex and an aldehyde. A series of reactions that regenerate the silylcopper complex were developed for the synthesis of an ahydroxycarboxylic acid. After repeating each step iteratively for two cycles, 0.62 equiv of alpha-hydroxycarboxylic acid based on the copper complex was obtained.

引用

收藏

页码：4922 / 4926

页数：5

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