Transition metal-catalyzed homodimerization of 1,3,5-cycloheptatrienes

被引：5

作者：

D'yakonov, V. A. ^{[1
]}

Kadikova, G. N. ^{[1
]}

Kolokol'tsev, D. I. ^{[1
]}

Khalilov, L. M. ^{[1
]}

Dzhemilev, U. M. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Petrochem & Catalysis, Ufa 450075, Bashkortostan, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2013年 / 62卷 / 02期

关键词：

cycloheptatrienes; metal complex catalysis; polycyclic hydrocarbons; cycloaddition; organoaluminum compounds; 6-PI+2-PI CYCLOADDITIONS; CYCLOHEPTATRIENE; ALLENES; DIMERS;

D O I：

10.1007/s11172-013-0060-y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New systems obtained by the treatment of Ti, Ni, Nb, Ta, and Zr compounds with diethylaluminum chloride catalyze the selective homodimerization of 1,3,5-cycloheptatrienes to form strained pentacyclic hydrocarbons via the mechanisms of [6+2] intermolecular and [4+2] intramolecular cycloaddition.

引用

页码：441 / 443

页数：3

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