Synthesis and properties of a thermo-/light-sensitive hydrogel

被引:0
作者
Li Lixia [1 ,2 ]
Xing Xiaodong [2 ]
Liu Zuliang [2 ]
Fan Haitao [2 ]
Hu Man [1 ]
机构
[1] Nanjing Univ Sci & Technol, Nanjing 210094, Jiangsu, Peoples R China
[2] Jiangsu Univ, Zhenjiang 212013, Peoples R China
来源
ADVANCED MATERIALS AND PROCESSES II, PTS 1-3 | 2012年 / 557-559卷
关键词
thermo-/light-sensitive hydrogel; copolymerization; N-isopropylacrylamide; phase transition; swelling; N-ISOPROPYLACRYLAMIDE; PHOTORESPONSIVE POLYMERS; AZOBENZENE; COPOLYMER; PH; TEMPERATURE; RELEASE; ACID; DRUG; GELS;
D O I
10.4028/www.scientific.net/AMR.557-559.1556
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A newly developed water-soluble azobenzene-containing monomer, 4-(4-((4-ethoxyphenyl)diazenyl)phenoxy)-N-(2-(methacryloyloxy)ethyl)-N,N-dimethylbutan-1-aminium bromide (assigned to M), was synthesized, and then a thermo-/light-sensitive gel was prepared by copolymerization of M and N-isopropylacrylamide. The properties of the gel were subsequently investigated by DSC, UV-vis, and gravimetry. The results showed that the copolymer hydrogel had a very quickly tran-cis photoisomerization rate upon UV irradiation. The critical solution temperature (CST) of the copolymer hydrogel could be toned by the M content and U, did also of the swelling ability.
引用
收藏
页码:1556 / +
页数:3
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