A novel oxidative desulfurization process to remove refractory sulfur compounds from diesel fuel

被引：187

作者：

Sampanthar, JT ^{[1
]}

Xiao, H ^{[1
]}

Dou, H ^{[1
]}

Nah, TY ^{[1
]}

Rong, X ^{[1
]}

Kwan, WP ^{[1
]}

机构：

[1] ASTAR, Appl Catalysis Technol Grp, Inst Chem & Engn Sci, Singapore 627833, Singapore

来源：

APPLIED CATALYSIS B-ENVIRONMENTAL | 2006年 / 63卷 / 1-2期

关键词：

oxidative desulfurization; diesel; sulfur; catalyst; MnO2/gamma-Al2O3; Co3O4/gamma-Al2O3; solvent extraction;

D O I：

10.1016/j.apcatb.2005.09.007

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Manganese and cobalt oxide catalysts supported on gamma-Al2O3 have been found to be effective in catalyzing air oxidation of the sulfur impurities in diesel to corresponding sulfones at a temperature range of 130-200 degrees C and atmospheric pressure. The sulfones were removed by extraction with polar solvent to reduce the sulfur level in diesel to as low as 40-60 ppm. Oxidation of model compounds showed that the most refractory sulfur compounds in hydrodesulfarization of diesel were more reactive in oxidation. The oxidative reactivity of model impurities in diesel follows the order: trialkyl-substituted dibenzothiophene > dialkyl-substituted dibenzothiophene > monoalkyl-substituted dibenzothiophene > dibenzothiophene. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：85 / 93

页数：9

共 32 条

[1]

[Anonymous], US Pat., Patent No. [6,406,616, 6406616]

[2] Deep desulfurization of diesel fuel by extraction with ionic liquids [J].

Bösmann, A ;

Datsevich, L ;

Jess, A ;

Lauter, A ;

Schmitz, C ;

Wasserscheid, P .

CHEMICAL COMMUNICATIONS, 2001, (23) :2494-2495

[3] Oxidative desulphurisation of oils via hydrogen peroxide and heteropolyanion catalysis [J].

Collins, FM ;

Lucy, AR ;

Sharp, C .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 117 (1-3) :397-403

[4] Desulfurization of transportation fuels by π-complexation sorbents:: Cu(I)-, Ni(II)-, and Zn(II)-zeolites [J].

Hernández-Maldonado, AJ ;

Yang, FH ;

Qi, G ;

Yang, RT .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2005, 56 (1-2) :111-126

[5] Desulfurization of diesel fuels by adsorption via π-complexation with vapor-phase exchanged Cu(l)-Y zeolites [J].

Hernández-Maldonado, AJ ;

Yang, RT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (04) :992-993

[6] Adsorption of thiophenes out of hydrocarbons using metal impregnated nanocrystalline aluminum oxide [J].

Jeevanandam, P ;

Klabunde, KJ ;

Tetzler, SH .

MICROPOROUS AND MESOPOROUS MATERIALS, 2005, 79 (1-3) :101-110

[7] Catalyst and process technologies for ultra low sulfur diesel [J].

Knudsen, KG ;

Cooper, BH ;

Topsoe, H .

APPLIED CATALYSIS A-GENERAL, 1999, 189 (02) :205-215

[8] Ultra-deep desulfurization of diesel: Oxidation with a recoverable catalyst assembled in emulsion [J].

Li, C ;

Jiang, ZX ;

Gao, JB ;

Yang, YX ;

Wang, SJ ;

Tian, FP ;

Sun, FX ;

Sun, XP ;

Ying, PL ;

Han, CR .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (09) :2277-2280

[9] Biodesulfurization of dibenzothiophene by a newly isolated bacterium Mycobacterium sp X7B [J].

Li, FL ;

Xu, P ;

Ma, CQ ;

Zheng, YA ;

Qu, YB .

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 2003, 36 (10) :1174-1177

[10] A new approach to deep desulfurization of gasoline, diesel fuel and jet fuel by selective adsorption for ultra-clean fuels and for fuel cell applications [J].

Ma, XL ;

Sun, L ;

Song, CS .

CATALYSIS TODAY, 2002, 77 (1-2) :107-116

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